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DOI: 10.1039/A902792K (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 1925-1928

A new class of macrocycle capable of binding exogenous metals: synthesis, structure, magnetic and electrochemical properties of a Cu(II) trinuclear complex based upon 1,4,8,11-tetraazacyclotetradecane-2,3-dione [exoO2]cyclam[hair space]†

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Leroy Cronin, Andrew R. Mount, Simon Parsons and Neil Robertson

Abstract

Synthesis of the new macrocycle 1,4,8,11-tetraazacyclo-tetradecane-2,3-dione [exo02]cyclam and its complexation with copper(II) ion via the tetraaza groups and linkd together through a copper(II) ion coordinated to the exo-cis oxygen donors of each macrocycle.

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