View PDF Version
 
DOI: 10.1039/A902228G (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 2477-2480

Synthesis, crystal structure and metamagnetic properties of a two-dimensional honeycomb network based on ferricyanide and (3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane)nickel(II) building blocks[hair space]†

(Note: The full text of this document is currently only available in the PDF Version )

Hui-Zhong Kou, Song Gao, Wei-Ming Bu, Dai-Zheng Liao, Bao-Qing Ma, Zong-Hui Jiang, Shi-Ping Yan, Yu-Guo Fan and Geng-Lin Wang

Abstract

The 2-D bimetallic complex [NiL]3[Fe(CN)6]2·9H2O (L represents 3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane) has been prepared and its structure and magnetic properties studied. The structure consists of cyano-bridged neutral Ni3Fe2 units. Each hexacyanoferrate(III) ion connects three nickel(II) ions using three cis CN– groups and the remaining CN– groups are terminal. The bridging cyanide ligands co-ordinate to the nickel ion in a trans fashion forming trans-NiL(N[triple bond, length half m-dash]C)2 moieties. The nine water molecules are situated between the 2-D layer and hydrogen bonded to the terminal CN– ligands. Magnetic studies show that the complex displays a metamagnetic behaviour originating from intralayer ferromagnetic coupling and interlayer antiferromagnetic interaction. A long-range magnetic ordering over the lattice at Tc = 5 K is also observed.

References

  1. R. Klenze, B. Kanellakopulos, G. Trageser and H. H. Eysel, J. Chem. Phys., 1980, 72, 5819 CrossRef.
  2. F. Herren, P. Fischer, A. Ludi and W. Halg, Inorg. Chem., 1980, 19, 956 CrossRef CAS.
  3. W. D. Griebler and D. Babel, Z. Naturforsch., Teil. B, 1982, 87, 832 Search PubMed.
  4. V. Gadet, T. Mallah, I. Castro and M. Verdaguer, J. Am. Chem. Soc., 1992, 114, 9213 CrossRef CAS.
  5. V. Gadet, M. Bujoli-Doeuff, L. Force, M. Verdaguer, K. El Malkhi, A. Deroy, J. P. Besse, C. Chappert, P. Veillet, J. P. Renard and P. Beauvillain, in Molecular Magnetic Materials, eds. D. Gatteschi, O. Kahn, J. S. Miller and P. Palacio, NATO ASI Ser. 198, Kluwer, Dordrecht, 1990, P. 281 Search PubMed.
  6. T. Mallah, S. Thiebaut, M. Verdaguer and P. Veillet, Science, 1993, 262, 1554 CrossRef CAS.
  7. W. R. Entley and G. S. Girolami, Inorg. Chem., 1994, 33, 5165 CrossRef CAS.
  8. W. R. Entley and G. S. Girolami, Science, 1995, 21, 268.
  9. S. Ferlay, T. Mallah, R. Ouaches, P. Veillet and M. Verdaguer, Nature (London), 1995, 378, 701 CrossRef CAS.
  10. O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Science, 1996, 271, 49 CrossRef CAS.
  11. M. Verdaguer, Science, 1996, 272, 698 CrossRef CAS.
  12. O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Science, 1996, 272, 704 CrossRef CAS.
  13. K. V. Langenberg, S. R. Batten, K. J. Berry, D. C. R. Hockless, B. Moubaraki and K. S. Murray, Inorg. Chem., 1997, 36, 5006 CrossRef.
  14. M. Ohba, N. Maruone, H. Okawa, T. Enoki and J.-M. Latour, J. Am. Chem. Soc., 1994, 116, 11566 CrossRef CAS; M. Ohba, N. Fukita and H. Okawa, J. Chem. Soc., Dalton Trans., 1997, 1733 RSC.
  15. H. Okawa and M. Ohba, ACS Symp. Ser., 1996, 644, 319 CAS; M. Ohba, N. Usuki, N. Fukita and H. Okawa, Inorg. Chem., 1998, 37, 3349 CrossRef CAS.
  16. M. Ohba, H. Okawa, T. Ito and A. Ohto, J. Chem. Soc., Chem. Commun., 1995, 1545 RSC; M. Ohba, H. Okawa, N. Fukita and Y. Hashimoto, J. Am. Chem. Soc., 1997, 119, 1011 CrossRef CAS.
  17. H.-Z. Kou, W.-M. Bu, D.-Z. Liao, P. Cheng, Z.-H. Jiang, S.-P. Yan, Y.-G. Fan and G.-L. Wang, J. Chem. Soc., Dalton Trans., 1998, 4161 RSC.
  18. M. S. El Fallah, E. Rentschler, A. Caneschi, R. Sessoli and D. Gatteschi, Angew. Chem., Int. Ed. Engl., 1996, 35, 1947 CrossRef CAS.
  19. S. Ferlay, T. Mallah, J. Vaissermann, F. Bartolome, P. Veillet and M. Verdaguer, Chem. Commun., 1996, 2481 RSC.
  20. H. Miyasaka, H. Ieda, N. Matsumoto, N. Re, R. Crescenzi and C. Floriani, Inorg. Chem., 1998, 37, 255 CrossRef CAS.
  21. H.-Z. Kou, D.-Z. Liao, P. Cheng, Z.-H. Jiang, S.-P. Yan, G.-L. Wang, X.-K. Yao and H.-G. Wang, J. Chem. Soc., Dalton Trans., 1997, 1503 RSC.
  22. M. Ohba and H. Okawa, Mol. Cryst. Liq. Cryst., 1996, 286, 101 Search PubMed.
  23. H. Miyasaka, N. Matsumoto, H. Okawa, N. Re, E. Gallo and C. Floriani, Angew. Chem., Int. Ed. Engl., 1995, 34, 1446 CrossRef CAS.
  24. H. Miyasaka, N. Matsumoto, H. Okawa, N. Re, E. Gallo and C. Floriani, J. Am. Chem. Soc., 1996, 118, 981 CrossRef CAS.
  25. N. Re, E. Gallo, C. Floriani, H. Miyasaka and N. Matsumoto, Inorg. Chem., 1996, 35, 5964 CrossRef CAS.
  26. H. Miyasaka, N. Matsumoto, N. Re, E. Gallo and C. Floriani, Inorg. Chem., 1997, 36, 670 CrossRef CAS.
  27. N. Re, R. Crescenzi, C. Floriani, H. Miyasaka and N. Matsumoto, Inorg. Chem., 1998, 37, 2717 CrossRef CAS.
  28. E. Colacio, J. M. Dominguez-Vera, M. Ghazi, R. Kivekas, M. Klinga and J. M. Moreno, Chem. Commun., 1998, 1071 RSC.
  29. M. P. Suh and S.-G. Kang, Inorg. Chem., 1988, 27, 2544 CrossRef CAS.
  30. C. K. Johnson, ORTEP, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.
  31. O. Kahn, in Molecular Magnetism, VCH, Weinheim, 1993 Search PubMed.
  32. A. Bohm, C. Vazquez, R. S. McLean, J. C. Calabrese, S. E. Kalm, J. L. Manson, A. J. Epstein and J. S. Miller, Inorg. Chem., 1996, 35, 3083 CrossRef.
Click here to see how this site uses Cookies. View our privacy policy here.