DOI: 10.1039/A901478K
(Paper)
Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 1043-1044
A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane
(Note: The full text of this document is currently only available in the PDF Version )
Belén Galán, Marta E. G. Mosquera, Julie S. Palmer, Paul R. Raithby and Dominic S. Wright
Abstract
Controlled hydrolysis of the cubane [SnNtBu]4 with H2O int thf-MeCN provides a direct route to the oxo complex [Sn4(NtBu)3O], reaction of which with naphNHLi (naph = 1-naphthyl) gives the heteroleptic cubane [Sn4(NtBu)3(Nnaph)] at the sole product.
References
- (a) M. Veith, M.-L. Sommer and D. Jäger, Chem. Ber., 1979, 112, 2581 CAS; (b) M. Veith and G. Schlemmer, Chem. Ber., 1982, 115, 2141 CAS; (c) M. Veith and M. Grosser, Z. Naturforsch., Teil B, 1982, 37, 1375 Search PubMed; (d) M. Veith and O. Recktenwald, Z. Naturforsch., Teil B, 1983, 38, 1054 Search PubMed.
- For other synthetic methods see: H. Chen, R. A. Bartlett, H. V. R. Dias, M. M. Olmstead and P. P. Power, Inorg. Chem., 1991, 30, 3390 Search PubMed; R. E. Allan, M. A. Beswick, A. J. Edwards, M. A. Paver, P. R. Raithby, M.-A. Rennie and D. S. Wright, J. Chem. Soc., Dalton Trans., 1995, 1991 CrossRef CAS.
- R. E. Allan, M. A. Beswick, N. L. Cromhout, M. A. Paver, P. R. Raithby, A. Steiner, M. Trevithick and D. S. Wright, Chem. Commun., 1996, 1501 RSC.
- M. Veith and H. Lange, Angew. Chem., Int. Ed. Engl., 1980, 19, 401 CrossRef; M. Veith and W. Frank, Angew. Chem., Int. Ed. Engl., 1985, 24, 223 CrossRef.
- (a) M. A. Beswick, M. E. G. Mosquera and D. S. Wright, J. Chem. Soc., Dalton Trans., 1998, 2437 RSC; (b) M. A. Beswick and D. S. Wright, Coord. Chem. Rev., 1998, 176, 1373 CrossRef CAS.
- A. G. Davies, Comprehensive Organometallic Chemistry II, eds. E. W. Abell, F. G. A. Stone and G. Wilkinson, Pergamon, Oxford, 1995, vol. 2, ch. 6, p. 217 Search PubMed.
- M. M. Olmstead and P. P. Power, Inorg. Chem., 1984, 23, 413 CrossRef CAS.
- D. Stalke and T. Kottke, J. Appl. Crystallogr., 1993, 25, 615.
- G. M. Sheldrick, SHELXL 93, a package for crystal structure refinement, University of Göttingen, 1993.
- C. K. Johnson, ORTEP, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.