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DOI: 10.1039/A901462D (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 1897-1910

Electrochemical molecular recognition: pathways between complexation and signalling

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Paul D. Beer, Philip A. Gale and George Z. Chen

Abstract

This perspective examines the mechanisms by which electrochemical recognition of various charged and neutral guest species by redox-active receptor molecules takes place. Particular emphasis is given to the intramolecular signalling pathway employed in each case. These include electrostatic interactions (through space or through conju-gated bonds), conformational changes in the redox centre in complexation and guest interference to an already present communication pathway in the host.

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