A novel polymeric copper(I) complex with an unusual azide bridge. Synthesis and crystal structure of [Cu(pyza)(µ-1,1,3-N₃)]_∞ (pyza = pyrazinecarboxamide)

Abstract

The first polymeric copper(I) complex with a µ-1,1,3-N₃ bridge [Cu(pyza)(µ-1,1,3-N₃)]_∞ (pyza = pyrazinecarboxamide) has been synthesized and characterized.

References

1. E. I. Solomon, M. J. Baldwin and M. D. Lowery, Chem. Rev., 1992, 92, 521.
2. See for example, (a) L. K. Thompson, S. S. Tandon and M. E. Manuel, Inorg. Chem., 1995, 34, 2356; (b) J. H. Satcher, Jun, M. W. Droege, T. J. R. Weakly and R. T. Taylor, Inorg. Chem., 1995, 34, 3317; (c) A. Escuer, R. Vicente, F. A. Mautner and M. A. S. Goher, Inorg. Chem., 1997, 36, 1233.
3. R. F. Ziolo, A. P. Gaughan, Z. Dori, C. G. Pierpont and R. Eisen-berg, Inorg. Chem., 1971, 10, 1289.
4. M. A. S. Goher and F. A. Mautner, Polyhedron, in the press.
5. S.-M. Kuang, Z.-Z. Zhang, Q.-G. Wang and T. C. W. Mak, J. Chem. Soc., Dalton Trans., 1997, 4477.
6. A. J. Blake, N. R. Champness, M. Crew, L. R. Hannon, S. Parsons and M. Schroder, J. Chem. Soc., Dalton Trans., 1998, 1533.