Crystalline TCNQ and TCNE adducts of the diborane(4) compounds B2(1,2-E2C6H4)2 (E = O or S)

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Todd B. Marder, Nicholas C. Norman, A. Guy Orpen, Michael J. Quayle and Craig R. Rice


Abstract

Crystal structures of 1∶1 adducts of diborane(4) compounds and the electron acceptors TCNQ and TCNE, namely B2(1,2-E2C6H4)2·TCNQ (E = O or S) and B2(1,2-E2C6H4)2·TCNE (E = O or S), have been found to show predominantly two-dimensional heteromolecular packing motifs with a variety of interlayer packings.


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