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DOI: 10.1039/A900619B (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 2337-2342

Linear trinuclear and one-dimensional copper(II) complexes containing co-bridging end-on azido and triazole ligands. Crystal structures and magnetic properties of [Cu3(atrz)2(N3)6] and [Cu(atrz)2(N3)]NO3 (atrz = 4-amino-1,2,4-triazole)

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Jia-Cheng Liu, De-Gang Fu, Jin-Zhong Zhuang, Chun-Ying Duan and Xiao-Zeng You

Abstract

New complexes with 1,2,4-triazole and end-on azido bridging ligands, [Cu3(atrz)2(N3)6] 1 and [Cu(atrz)2(N3)]NO32 (atrz = 4-amino-1,2,4-triazole), have been prepared and structurally determined. Complex 1 has a linear trinuclear copper(II) structure with bridging bond angles Cu–N–N (atrz) [119.3(3) and 123.4(3)°], and larger Cu–N–Cu [118.7(2)°]. In 2 the copper(II) ions are linked by one end-on azido and two triazole bridges forming a cationic chain with Cu–N–N (equatorial atrz) [121.0(2) and 122.3(2)°] and Cu–N–Cu 104.05(12)°. The nearest-neighbour Cu[hair space][hair space]· · ·[hair space][hair space]Cu distances are 3.4496(7) Å for 1 and 3.5034(6) Å for 2. The copper(II) ions are strongly antiferromagnetically coupled with J = –108.8 cm–1 for 1, and weakly with J = –17.7 cm–1 for 2. The nature and the magnitude of the antiferromagnetic exchange of both complexes are discussed based on their structures.

References

  1. R. Prins, P. J. M. W. L. Birker, J. G. Haasnoot, G. C. Verschoor and J. Reedijk, Inorg. Chem., 1985, 24, 4128 CrossRef CAS.
  2. A. Bencini, D. Gatteschi, C. Zanchini, J. G. Haasnoot, R. Prins and J. Reedijk, Inorg. Chem., 1985, 24, 2812 CrossRef CAS.
  3. P. M. Slangen, P. J. van Koningsbruggen, J. G. Haasnoot, J. Jansen, S. Gorter, J. Reedijk, H. Kooijman, W. J. J. Smeets and A. L. Spek, Inorg. Chim. Acta, 1993, 212, 289 CrossRef CAS.
  4. P. M. Slangen, P. J. van Koningsbruggen, K. Goubitz, J. G. Haasnoot and J. Reedijk, Inorg. Chem., 1994, 33, 1121 CrossRef.
  5. W. M. E. Koomen-van Oudenniel, R. A. G. de Graaff, J. G. Haasnoot, R. Prins and J. Reedijk, Inorg. Chem., 1989, 28, 1128 CrossRef CAS.
  6. P. J. van Koningsbruggen, J. G. Haasnoot, R. A. G. de Graaff, J. Reedijk and S. Slingerland, Acta Crystallogr., Sect. C, 1992, 48, 1923 CrossRef.
  7. P. J. van Koningsbruggen, J. G. Haasnoot, H. Kooijman, J. Reedijk and A. L. Spek, Inorg. Chem., 1997, 36, 2487 CrossRef CAS.
  8. Y. Garcia, P. J. van Koningsbruggen, G. Bravic, P. Guionneau, D. Chasseau, G. L. Cascarano, J. Moscovici, K. Lambert, A. Michalowicz and O. Kahn, Inorg. Chem., 1997, 36, 6357 CrossRef CAS.
  9. P. J. van Koningsbruggen, J. G. Haasnoot, W. Vreugdenhil, J. Reedijk and O. Kahn, Inorg. Chim. Acta, 1995, 239, 5 CrossRef CAS; D. J. Mackey and R. L. Martin, J. Chem. Soc., Dalton Trans., 1978, 702 RSC.
  10. P. J. van Koningsbruggen, J. W. van Hal, R. A. G. de Graaff, J. G. Haasnoot and J. Reedijk, J. Chem. Soc., Dalton Trans., 1993, 2163 RSC.
  11. G. A. van Albada, R. A. G. de Graaff, J. G. Haasnoot and J. Reedijk, Inorg. Chem., 1984, 23, 1404 CrossRef; F. J. Rietmeijer, G. A. van Albada, R. A. G. de Graaff, J. Haasnoot and J. Reedijk, Inorg. Chem., 1985, 24, 3597 CrossRef CAS.
  12. G. Vos, R. A. le Fêbre, R. A. G. de Graaff, J. G. Haasnoot and J. Reedijk, J. Am. Chem. Soc., 1983, 105, 1682 CrossRef CAS; G. Vos, R. A. G. de Graaff, J. G. Haasnoot, A. M. van der Kraan, P. de Vaal and J. Reedijk, Inorg. Chem., 1984, 23, 2905 CrossRef; J. Kröber, E. Codjovi, O. Kahn, F. Grolière and C. Jay, J. Am. Chem. Soc., 1993, 115, 9810 CrossRef CAS; M. Thomann, O. Kahn, J. Guilhem and F. Varret, Inorg. Chem., 1994, 33, 6029 CrossRef CAS; J. J. A. Kolnaar, G. van Dijk, H. Kooijman, A. L. Spek, V. G. Ksenofontov, P. Gütlich, J. G. Haasnoot and J. Reedijk, Inorg. Chem., 1997, 36, 2433 CrossRef CAS; Y. Garcia, P. J. van Koningsbruggen, E. Codjovi, R. Lapouyade, O. Kahn and L. Rabardel, J. Mater. Chem., 1997, 7, 857 RSC; P. J. van Koningsbruggen, Y. Garcia, E. Codjovi, R. Lapouyade, L. Fournès, O. Kahn and L. Rabardel, J. Mater. Chem., 1997, 7, 2069 RSC.
  13. O. Kahn, Molecular Magnetism, VCH, New York, 1993 Search PubMed.
  14. S. S. Tandon, L. K. Thompson, M. E. Manuel and J. N. Bridson, Inorg. Chem., 1994, 33, 5555 CrossRef CAS.
  15. L. K. Thompson, S. S. Tandon and M. E. Manuel, Inorg. Chem., 1995, 34, 2356 CrossRef.
  16. R. M. Herbst and J. A. Garrison, J. Org. Chem., 1953, 18, 872 CrossRef CAS.
  17. Siemens, SHELXTL, Version 5.0, Siemens Industrial Automation, Inc., Analytical Instrumentation, Madison, WI, 1995.
  18. I. Agrell, Acta Chem. Scand., 1969, 23, 1667 CAS; F. A. Mautner and M. A. S. Goher, Polyhedron, 1994, 13, 2141; 1993, 12, 2823 Search PubMed; J. Lorösch, H. Paulus and W. Haase, Inorg. Chim. Acta, 1985, 106, 101 Search PubMed.
  19. J. A. Jarvis, Acta Crystallogr., 1962, 15, 964 CrossRef CAS.
  20. M. A. S. Goher and T. C. W. Mak, Inorg. Chim. Acta, 1985, 99, 223 CrossRef CAS; T. C. W. Mak and M. A. S. Goher, Inorg. Chim. Acta, 1986, 115, 17 CrossRef CAS.
  21. J. Comarmond, P. Plumeré, J.-M. Lehn, Y. Agnus, R. Louis, R. Weiss, O. Kahn and I. Morgenstern-Badarau, J. Am. Chem. Soc., 1982, 104, 6330 CrossRef.
  22. W. Vreugdenhil, J. G. Haasnoot, J. Reedijk and J. S. Wood, Inorg. Chim. Acta, 1990, 167, 109 CrossRef CAS.
  23. R. Cortés, M. K. Urtiaga, L. Lezama, J. I. R. Larramendi, M. I. Arriortua and T. Rojo, J. Chem. Soc., Dalton Trans., 1993, 3685 RSC.
  24. E. Sinn, Coord. Chem. Rev., 1970, 5, 313 CrossRef CAS; D. B. Brown, J. R. Wasson, J. W. Hall and W. E. Hatfield, Inorg. Chem., 1977, 16, 2526 CrossRef CAS.
  25. B. E. Myers, L. Berger and S. A. Friedberg, J. Appl. Phys., 1969, 40, 1149 CrossRef CAS.
  26. A. P. Ginsberg, R. L. Martin, R. W. Brookes and R. C. Sherwood, Inorg. Chem., 1972, 11, 2884 CrossRef CAS.
  27. A. Escuer, R. Vicente, F. A. Mautner and M. A. S. Goher, Inorg. Chem., 1997, 36, 1233 CrossRef CAS.
  28. J. C. Bonner and M. E. Fisher, Phys. Rev. A, 1964, 135, 640; W. E. Estes, D. P. Gavel, W. E. Hatfield and D. Hodgson, Inorg. Chem., 1978, 17, 1415 CrossRef CAS.
  29. A. Escuer, R. Vicente, B. Mernari, A. E. Gueddi and M. Pierrot, Inorg. Chem., 1997, 36, 2511 CrossRef CAS.
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