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DOI: 10.1039/A900615J (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 823-824

Spectroscopic and structural characterisation of fac-[Mn(CO)3{MeC(CH2TeMe)3}]CF3SO3: the first transition metal complex of a tritelluroether

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William Levason, Simon D. Orchard and Gillian Reid

Abstract

The preparation and crystal structure of the first complex of a multidentate, fac-[Mn(CO)3{MeC(CH2-TeMe)3}]CF3SO3 are described, and multinuclear NMR spectroscopic studies suggest that the telluroether is a significantly better σ-donor to Mn(I compared to its selenoether analogue.

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