View PDF Version
 
DOI: 10.1039/A900569B (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 1813-1818

Novel sheet-like manganese(II) networks. Synthesis and structure of [Mn(bpe)(NCS)2(CH3OH)2] and [Mn(bpe)(NCS)2(CH3OH)2]·bpe [bpe = trans-1,2-bis(4-pyridyl)ethene]

(Note: The full text of this document is currently only available in the PDF Version )

Giovanni De Munno, Donatella Armentano, Teresa Poerio, Miguel Julve and José Antonio Real

Abstract

Two new manganese(II) compounds of formula [Mn(bpe)(NCS)2(CH3OH)2] 1 and [Mn(bpe)(NCS)2(CH3OH)2]·bpe 2 [bpe = trans-1-2-bis(4-pyridyl)ethene] have been synthesized and characterized by single-crystal X-ray diffraction. The structures of compounds 1 and 2 consist of neutral chains containing manganese(II) ions bridged by mutually trans bpe molecules, the substantial difference being the bpe crystallization molecules which are in 2 and not in 1. In both compounds the six-co-ordination of Mn2+ is achieved by means of two trans NCS– ions and methanol molecules. In 1 adjacent chains are connected through weak hydrogen bonds in such a way to form a two-dimensional structure, in which rectangular holes are present. The Mn[hair space][hair space]· · ·[hair space][hair space]Mn distance through the bpe bridge is 14.06(1) Å whereas that through the thiocyanate–methanol bridge is 6.73(1) or 7.54(1) Å. In 2 adjacent chains are linked through hydrogen bonds involving two nitrogen atoms of the solvate bpe molecule and two hydroxo groups from two methanol molecules in order to form layers. In each of these, four Mn2+ ions occupy the corners of a rectangle, which is constituted by four metal ions, four bpe and four methanol molecules. The Mn[hair space][hair space]· · ·[hair space][hair space]Mn distances through co-ordinated and hydrogen-bonded bpe are 13.93(1) and 17.10(1) Å. Adjacent sheets are shifted in such a way that metal ions of the first approximately correspond to the center of the hole of the second one and vice versa.

References

  1. G. R. Desiraju, in Crystal Engineering: Design of Organic Solids, Elsevier, Amsterdam, 1989 Search PubMed; Angew. Chem., Int. Ed. Engl., 1995, 34, 2311 Search PubMed.
  2. J. M. Lehn, Supramolecular Chemistry, VCH, Weinheim, 1985, ch. 9 Search PubMed; Angew. Chem., Int. Ed. Engl., 1997, 27, 89 Search PubMed.
  3. R. Robin, B. F. Abrahams, R. R. Barten, R. W. Gable, B. F. Huskiness and J. Lieu, Supramolecular Architecture, ACS publication, Washington DC, 1992, ch. 19 Search PubMed.
  4. D. B. Amabilino, C. O. Dietrich-Buchecker, A. Livoreil, L. Pérez-García, J. P. Sauvage and J. F. Stoddart, in Magnetism: A Supramolecular Function, ed. O. Kahn, NATO ASI Ser. C, Kluwer, Dordrecht, 1996, vol. 484, p. 65 Search PubMed.
  5. M. Munakata, L. P. Wu, M. Yamamoto, T. Kuroda-Sowa and M. Maekawa, J. Am. Chem. Soc., 1996, 118, 3117 CrossRef CAS.
  6. C. B. Aakeröy, A. M. Beatty and B. A. Helfrich, J. Chem. Soc., Dalton Trans., 1998, 1943 RSC.
  7. S. R. Batten and R. Robson, Angew. Chem., Int. Ed. Engl., 1998, 37, 1460 CrossRef.
  8. C. L. Bowes and G. A. Ozin, Adv. Mater., 1996, 8, 13 CAS.
  9. B. Olcnyuk, A. Fechtenkötter and P. J. Stang, J. Chem. Soc., Dalton Trans., 1998, 1707 RSC.
  10. A. J. Blake, N. R. Champness, M. Crew, L. R. Hanton, S. Parsons and M. Schröder, J. Chem. Soc., Dalton Trans., 1998, 1533 RSC.
  11. F. Lloret, G. De Munno, M. Julve, J. Cano, R. Ruiz and A. Caneschi, Angew. Chem., Int. Ed. Engl., 1998, 37, 135 CrossRef CAS.
  12. L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, J. Am. Chem. Soc., 1995, 117, 4562 CrossRef CAS.
  13. J. A. Real, G. De Munno, M. C. Muñoz and M. Julve, Inorg. Chem., 1991, 30, 2701 CrossRef CAS.
  14. M. L. Tong, X. M. Chen, X. L. Yu and T. C. W. Mak, J. Chem. Soc., Dalton Trans., 1998, 5 RSC.
  15. M. L. Tong, B. H. Ye, J. W. Cai, X. M. Chen and S. W. Ng, Inorg. Chem., 1998, 37, 2645 CrossRef CAS.
  16. L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, J. Chem. Soc., Dalton Trans., 1997, 1801 RSC.
  17. J. Li, H. Zeng, J. Chen, Q. Wang and X. Wu, Chem. Commun., 1997, 1213 RSC.
  18. J. Lu, T. Paliwala, S. C. Lim, C. Yu, T. Nju and A. J. Jacobson, Inorg. Chem., 1997, 36, 923 CrossRef CAS.
  19. O. M. Yaghi and H. Li, J. Am. Chem. Soc., 1995, 117, 10401 CrossRef CAS.
  20. S. Subramanian and M. Zaworotko, Angew. Chem., Int. Ed. Engl., 1995, 34, 2127 CrossRef CAS.
  21. F. Robinson and M. Zaworotko, J. Chem. Soc., Chem. Commun., 1995, 2413 RSC.
  22. M. X. Li, G. H. Xie, Y. D. Gu, J. Chen and P. J. Zheng, Polyhedron, 1995, 14, 1235 CrossRef CAS.
  23. M. Fujita, Y. J. Kwron, S. Washizu and K. Ogura, J. Am. Chem. Soc., 1994, 116, 1151 CrossRef CAS.
  24. A. J. Blake, S. J. Hill, P. Hubberstey and W.-S. Li, J. Chem. Soc., Dalton Trans., 1997, 913 RSC.
  25. A. J. Blake, N. R. Champness, S. S.-M. Chung, W. S. Li and M. Schröder, Chem. Commun., 1997, 1005 RSC.
  26. J. A. Real, E. Andrés, M. C. Muñoz, M. Julve, T. Granier, A. Bousseksou and F. Varret, Science, 1995, 268, 265 CrossRef CAS.
  27. D. Hagrman, R. C. Haushalter and J. Zubieta, Chem. Mater., 1998, 10, 361 CrossRef CAS.
  28. D. Hagrman, R. P. Hammond, R. C. Haushalter and J. Zubieta, Chem. Mater., 1998, 10, 2091 CrossRef CAS.
  29. J. S. Haynes, A. Kostikas, J. R. Sams, A. Slmopoulos and R. C. Thompson, Inorg. Chem., 1987, 26, 2630 CrossRef CAS.
  30. SHELXL PLUS, version 4.11/V, Siemens Analytical X-Ray Instruments Inc., Madison, WI, 1990.
  31. M. Nardelli, Comput. Chem., 1983, 7, 95 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.