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DOI: 10.1039/A809725I (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 1509-1514

Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with µ-alkoxo bridges[hair space]†

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Satoshi Nishino, Hiroyuki Hosomi, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii and Yuzo Nishida

Abstract

Several dinuclear iron(III) complexes with µ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.

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