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DOI: 10.1039/A809323G (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 271-272

An unprecedented κ2N,H bonding mode for a hydridotris(pyrazolyl)borato ligand

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François Malbosc, Philippe Kalck, Jean-Claude Daran and Michel Etienne

Abstract

An unprecedented κ2N,H bonding mode for a hydridotris(pyrazolyl)borato (TpMe2,4-Cl) ligand is observed in [Rh(CO)(PMePh2)2(TpMe2,4-Cl)]; the complex, which features two dangling pyrazole rings and a B–(µ-H)–Rh agostic bond, is highly fluxional in solution.

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