View PDF Version
 
DOI: 10.1039/A808778D (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 901-908

Structural, vibrational and solid state CP MAS 31P NMR spectroscopic studies of complexes of trimethylphosphine with copper(I) and silver(I) halides

(Note: The full text of this document is currently only available in the PDF Version )

Graham A. Bowmaker, Eban N. de Silva, Peter C. Healy, Brian W. Skelton and Allan H. White

Abstract

New copper(I) and silver(I) halide–trimethylphosphine adducts have been prepared by reaction of MX with PMe3 in benzene suspension, and characterised by room-temperature single-crystal X-ray studies and/or solid state CP MAS 31P NMR and vibrational spectroscopy. The complex [Ag4Cl4(PMe3)3] is a one-dimensional polymer of quasi-cubanoid Ag4Cl4 units disposed with their body diagonals coincident with the crystallographic 3 axis, and linked by Ag–Cl units between the four-co-ordinate apical atoms of successive Ag4Cl4 units, isomorphous with its Cu counterpart. The first solid state NMR study of Cu/Ag PMe3 complexes is reported. The CP MAS 31P NMR and the far-IR and Raman spectra of the complexes [{CuI(PMe3)}4], [CuCl(PMe3)3] and [{AgX(PMe3)2}2] (X = Cl or Br) show the structures to be tetrameric cubane, monomeric pseudo-tetrahedral and dimeric halide-bridged respectively.

References

  1. G. A. Bowmaker, R. D. Hart, B. E. Jones, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1995, 3063 RSC.
  2. G. A. Bowmaker, P. C. Healy, J. D. Kildea and A. H. White, Spectrochim. Acta., Part A, 1988, 44, 1219 CrossRef.
  3. G. A. Bowmaker, J. V. Hanna, R. D. Hart, P. C. Healy and A. H. White, Aust. J. Chem., 1994, 47, 25 CAS.
  4. G. A. Bowmaker, R. J. Knappstein and Suit Fong Tham, Aust. J. Chem., 1978, 31, 2137 CAS.
  5. S. Attar, N. W. Alcock, G. A. Bowmaker, J. S. Frye, W. H. Bearden and J. H. Nelson, Inorg. Chem., 1991, 30, 4166 CrossRef CAS.
  6. S. Attar, G. A. Bowmaker, N. W. Alcock, J. S. Frye, W. H. Bearden and J. H. Nelson, Inorg. Chem., 1991, 30, 4743 CrossRef CAS.
  7. G. A. Bowmaker, Effendy, J. V. Hanna, P. C. Healy, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1993, 1387 RSC.
  8. H. Schmidbaur, J. Adlkofer and K. Schwirten, Chem. Ber., 1972, 105, 3382 CAS.
  9. K. M. Chi, J. Farkas, M. J. Hampden-Smith, T. T. Kodas and E. N. Duesler, J. Chem. Soc., Dalton Trans., 1992, 3111 RSC.
  10. H. G. M. Edwards, Spectrochim. Acta, Part A, 1986, 42, 1401 CrossRef.
  11. R. J. Goodfellow, J. G. Evans, P. L. Goggin and D. A. Duddell, J. Chem. Soc. A, 1968, 1604 RSC.
  12. D. A. Duddell, P. L. Goggin, R. J. Goodfellow, M. G. Norton and J. G. Smith, J. Chem. Soc. A, 1970, 545 RSC.
  13. K. Angermaier, G. A. Bowmaker, E. N. de Silva, P. C. Healy, B. E. Jones and H. Schmidbaur, J. Chem. Soc., Dalton Trans., 1996, 3121 RSC.
  14. M. L. Luetkens, Jr., A. P. Sattelberger, H. H. Murray, J. D. Basil and J. P. Fackler, Jr., Inorg. Synth., 1990, 28, 305.
  15. S. R. Hall, H. D. Flack and J. M. Stewart, XTAL Reference Manual Version 3.2, Universities of Western Australia, Geneva and Maryland, 1992 Search PubMed.
  16. P. C. Healy, C. Pakawatchai, C. L. Raston, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1983, 1905 RSC.
  17. B. K. Teo and J. C. Calabrese, Inorg. Chem., 1976, 15, 2467 CrossRef CAS.
  18. N. A. Bell, M. Goldstein, T. Jones and I. W. Nowell, Inorg. Chim. Acta, 1981, 48, 185 CrossRef CAS.
  19. G. A. Bowmaker, J. V. Hanna, R. D. Hart, P. C. Healy and A. H. White, J. Chem. Soc., Dalton Trans., 1994, 2621 RSC.
  20. P. F. Barron, J. C. Dyason, P. C. Healy, L. M. Engelhardt, C. Pakawatchai, V. A. Patrick and A. H. White, J. Chem. Soc., Dalton Trans., 1987, 1099 RSC.
  21. P. F. Barron, J. C. Dyason, L. M. Engelhardt, P. C. Healy and A. H. White, Aust. J. Chem., 1985, 38, 261 CAS.
  22. E. M. Menger and W. S. Veeman, J. Magn. Reson., 1982, 46, 257 CAS.
  23. R. K. Harris and A. C. Olivieri, Prog. Nucl. Magn. Reson. Spectrosc., 1992, 24, 435 CrossRef CAS.
  24. J. V. Hanna, M. E. Smith, S. N. Stuart and P. C. Healy, J. Phys. Chem., 1992, 96, 7560 CrossRef CAS.
  25. A. Olivieri, J. Am. Chem. Soc., 1992, 114, 5758 CrossRef CAS.
  26. S. H. Alarcon, A. C. Olivieri and R. K. Harris, Solid State Nucl. Magn. Reson., 1993, 2, 325 CrossRef CAS.
  27. J. V. Hanna, R. D. Hart, P. C. Healy, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1998, 2321 RSC.
  28. D. F. Dempsey and G. S. Girolami, Organometallics, 1988, 7, 1208 CrossRef CAS.
  29. G. A. Bowmaker, P. C. Healy, L. M. Engelhardt, J. D. Kildea, B. W. Skelton and A. H. White, Aust. J. Chem., 1990, 43, 1697 CAS.
  30. G. A. Bowmaker, L. D. Brockliss and R. Whiting, Aust. J. Chem., 1973, 26, 29 CAS.
  31. M. R. Churchill, B. G. DeBoer and S. J. Mendak, Inorg. Chem., 1975, 14, 2041 CrossRef CAS.
  32. M. R. Churchill and K. L. Kalra, Inorg. Chem., 1974, 13, 1899 CrossRef CAS.
  33. T. Okuda, M. Hiura, K. Yamada and H. Negita, Chem. Lett., 1977, 367 CAS.
  34. L.-J. Baker, G. A. Bowmaker, D. Camp, Effendy, P. C. Healy, H. Schmidbaur, O. Steigelmann and A. H. White, Inorg. Chem., 1992, 31, 3656 CrossRef CAS.
  35. G. A. Bowmaker, Effendy, P. J. Harvey, P. C. Healy, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1996, 2449 RSC.
  36. G. A. Bowmaker, Effendy, P. J. Harvey, P. C. Healy, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1996, 2459 RSC.
  37. P. F. Barron, J. C. Dyason, P. C. Healy, L. M. Engelhardt, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1986, 1965 RSC.
  38. H. G. M. Edwards and D. W. Farwell, J. Mol. Struct., 1989, 197, 203 CrossRef CAS.
  39. G. A. Bowmaker and P. C. Healy, Spectrochim. Acta, Part A, 1988, 44, 115 CrossRef.
  40. G. A. Bowmaker, R. D. Hart, E. N. de Silva, B. W. Skelton and A. H. White, Aust. J. Chem., 1997, 50, 553 CrossRef CAS.
  41. D. N. Waters and B. Basak, J. Chem. Soc. A, 1971, 2733 RSC.
  42. G. A. Bowmaker, Effendy, J. D. Kildea and A. H. White, Aust. J. Chem., 1997, 50, 577 CrossRef.
Click here to see how this site uses Cookies. View our privacy policy here.