Construction of a unique three-dimensional array with cadmium(II)[hair space]

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Arunendu Mondal, Golam Mostafa, Ashutosh Ghosh, Inamur Rahaman Laskar and Nirmalendu Ray Chaudhuri


Abstract

The complex [Cd3(dien)2(NCS)6]n·nH2O (dien = diethylenetriamine) is prepared and characterised by X-ray diffraction studies, which show a new type of three-dimensional polymeric structure having cadmium centres which are linked to each other via NCS bridges in such a way that two types of Cd environment (one involving only N-donor atoms and the other only S-donor atoms) are produced.


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