Insitu size determination of single levitated solid aerosols

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B. Berge, K. Sudholz, B. Steiner, J. Rohmann and E. Rühl


Abstract

An insitu sizing technique for single levitated solid aerosols is reported. The particle size is investigated in micrometre-sized sodium chloride particles, where the size and state of matter depend strongly on the ambient humidity. The experimental approach makes use of elastic light scattering from the particles that are levitated in an electrodynamic aerosol trap, where the patterns of scattered light are fast Fourier transformed for size determination. It is shown that this approach requires for solid particles short detection times of the scattered light, typically of the order of 0.1 ms, so that the solid particle can be treated as almost stationary in the trap. Size calibration of the fast Fourier transforms of the light scattering patterns is obtained by correlating the space frequency with the equivalent edge length. Deviations from a linear correlation are interpreted as evidence for the occurrence of non-cubic crystal shapes. This result is in agreement with additional experiments using conventional light microscopy.


References

  1. H. R. Pruppacher and J. D. Klett, Microphysics of Clouds and Precipitation, Kluwer, Dordrecht, 1997 Search PubMed.
  2. J. M. Haywood, V. Ramaswamy and B. J. Soden, Science, 1999, 283, 1299 CrossRef CAS; J. R. Carlton, S. E. Schwartz, J. M. Hales, R. D. Cess, J. A. Coakley, Jr., J. E. Hansen and D. J. Hofmann, Science, 1992, 255, 423 CrossRef CAS.
  3. R. P. Turco, T. W. Toon and P. Hamill, J. Geophys. Res., 1989, 94, 16493.
  4. J. Levefield and J. Heintzenberg, Science, 1992, 258, 117; X. Bao and J. L. Collett, Jr., Environ. Sci. Technol., 1995, 29, 1023.
  5. J. M. Pacyna in Airborne Particulate Matter, ed. T. Kouimtzis and C. Samara, Springer, Berlin, 1995, p. 69 Search PubMed.
  6. P. Warneck, Chemistry of the Natural Atmosphere, Academic Press, San Diego, 1988 Search PubMed.
  7. Atmospheric Aerosols and Nucleation, ed. P. E. Wagner and G. Vali, Lecture Notes in Physics, vol. 309, Springer, Berlin, 1988 Search PubMed.
  8. C. Levoni, M. Cevino, R. Guzzi and F. Torricella, Appl. Opt., 1997, 30, 8031.
  9. Advances in Atmospheric Remote Sensing with Lidar, ed. A. Ansmann, R. Neuber, P. Rairoux and U. Wandlinger, Springer, Berlin 1997 Search PubMed.
  10. I. N. Tang, J. Aerosol Sci., 1976, 7, 361 CAS.
  11. I. N. Tang, A. C. Tridico and K. H. Fung, J. Geophys. Res., 1997, 102, 23269 CAS.
  12. I. N. Tang, H. R. Munkelwitz and J. G. Davis, J. Aerosol Sci., 1978, 9, 505 CAS.
  13. D. G. Imre, J. Xu and A. C. Tridico, Geophys. Res. Lett., 1997, 24, 69 CrossRef CAS.
  14. B. Krämer, M. Schwell, O. Hübner, H. Vortisch, T. Leisner, E. Rühl, H. Baumgärtel and L. Wöste, Ber. Bunsen-Ges. Phys. Chem., 1996, 100, 1911.
  15. B. Krämer, M. Schwell, O. Hübner, H. Vortisch, E. Rühl, H. Baumgärtel, L. Wöste and T. Leisner, J. Chem. Phys., 1999, in the press Search PubMed.
  16. A. K. Ray, A. Souryri, E. J. Davis and T. M. Allen, Appl. Opt., 1991, 30, 3974 CrossRef CAS.
  17. M. Trunk, J. F. Lübben, J. Popp, B. Schrader and W. Kiefer, Appl. Opt., 1997, 36, 3305 CAS.
  18. I. N. Tang and H. R. Munkelwitz, Aerosol Sci. Technol., 1991, 15, 201 CAS.
  19. C. Roth and J. Gebhart, Part. Part. Syst. Charact., 1996, 13, 192 CAS.
  20. K. Dessens, Q. J. R. Meteorol. Soc., 1949, 75, 23 Search PubMed; S. Twomey, J. Meteorol., 1954, 11, 334 Search PubMed.
  21. C. H. Keith and A. B. Arons, J. Meteorol., 1954, 11, 173 Search PubMed.
  22. L. R. Watson, J. M. van Doren, P. Davidovitz, D. R. Worsnop, M. S. Zahniser and C. E. Kolb, J. Geophys. Res., 1990, 96, 5631.
  23. C. Zetsch and W. Behnke, Ber. Bunsen-Ges. Phys. Chem., 1992, 96, 488 CAS.
  24. A. Ashkin, Phys. Rev. Lett., 1970, 24, 156 CrossRef CAS; R. Thurn and W. Kiefer, Appl. Spectrosc., 1984, 38, 78 CAS; R. Thurn and W. Kiefer, Appl. Opt., 1985, 24, 1515 CrossRef CAS.
  25. W. Paul, Rev. Mod. Phys., 1990, 62, 531 CrossRef CAS; R. F. Wuerker, H. Shelton and R. V. Langmuir, J. Appl. Phys., 1959, 30, 342.
  26. E. J. Davis, Langmuir, 1985, 1, 379 CrossRef CAS; E. J. Davis, Aerosol Sci. Technol., 1997, 26, 212 CAS.
  27. S. Arnold and L. M. Folan, Rev. Sci. Instrum., 1985, 56, 2066 CrossRef CAS; S. Arnold, Rev. Sci. Instrum., 1991, 62, 3025 CrossRef CAS.
  28. P. Winkler and C. E. Junge, J. Rech. Atmos., 1972, 6, 617 Search PubMed.
  29. R. Finsy, Adv. Colloid Interface Sci., 1994, 52, 79 CrossRef CAS.
  30. H. C. van de Hulst, Light Scattering by Small Particles, Dover, New York, 1981 Search PubMed.
  31. M. Kerker, The Scattering of Light and Other Electromagnetic Radiation, Academic Press, 1969 Search PubMed.
  32. C. F. Bohren and D. R. Huffman, Absorption and Scattering of Light by Small Particles, Wiley, New York, 1983 Search PubMed.
  33. H. Umhauer and M. Bottlinger, Appl. Opt., 1991, 30, 4980.
  34. K. Anders, N. Roth and A. Frohn, J. Geophys. Res., 1996, 101, 19223 CAS.
  35. I. Kirmaci and G. Ward, Appl. Opt., 1979, 18, 3329.
  36. N. E. Chayen, E. H. Snell, J. R. Helliwell and P. F. Zagalsky, J. Crystal Growth, 1997, 171, 219 CrossRef CAS.
  37. E. M. Prucell and C. R. Pennypacker, Astrophys. J., 1973, 186, 171.
  38. B. Steiner, B. Berge, R. Gausmann, J. Rohmann and E. Rühl, Appl. Opt., 1999, 38, 1523 CAS.
  39. D. C. Taflin, S. H. Zhang, T. Allen and E. J. Davis, AIChE J., 1988, 34, 1310 CAS.
  40. M. D. Barnes, N. Lermer, W. B. Whitten and J. M. Ramsey, Rev. Sci. Instrum., 1997, 68, 2287 CrossRef CAS.
  41. I. N. Tang and H. R. Munkelwitz, J. Appl. Meteorol., 1994, 33, 791 Search PubMed.
  42. H.-C. Hansson, M. J. Rood, S. Koloutsou-Vakakis, K. Kämeri, D. Orsini and A. Wiedensohler, J. Atmos. Chem., 1998, 31, 321 CrossRef CAS.
  43. M. Vollmer, Kinetik der Phasenbildung, vol. IV, in Die chemische Reaktion, ed. K. F. Bonhoeffer, Steinkopf, Leipzig, 1939 Search PubMed.
  44. H. Motegi, T. Emoto, T. Ozaki and E. Nakamura, Jpn. J. Appl. Phys., 1978, 17, 717 CAS.
  45. Z. Zolc and O. Söhnel, Krist. Tech., 1973, 8, 811 Search PubMed.
  46. C. Heffels, D. Heizmann, E. D. Hirleman and B. Scarlett, Appl. Opt., 1995, 34, 6552 CAS.
  47. B. Berge, B. Steiner and E. Rühl, unpublished work.
  48. A. S. Wexler and J. H. Seinfeld, Atmos. Environ., Part A, 1991, 25, 2731.
  49. E. J. Davis in Aerosol Measurement, ed. K. Willeke and P. A. Baron, Wiley, New York, 1993, p. 452 Search PubMed.
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