Effects of oxygen on the Bray–Liebhafsky reaction

Abstract

The reactions of oxygen are not a necessary part of the explanation of the oscillations in the Bray–Liebhafsky reaction. However, oxygen can modify the shape of the oscillations and the range of concentrations where they are observed. We discuss the mechanism previously proposed and suggest that the chemical effects of oxygen result mainly from the oxidation of iodide by radical processes. The escape of oxygen has also a physical effect, the loss of iodine in the gas phase. The effects of light and stirring rate are related to the effects of oxygen.

References

1. W. C. Bray, J. Am. Chem. Soc., 1921, 43, 1262.
2. W. C. Bray and H. A. Liebhafsky, J. Am. Chem. Soc., 1931, 53, 38.
3. R. M. Noyes, J. Phys. Chem., 1990, 94, 4404 and references therein.
4. S. D. Furrow, in Oscillations and Travelling Waves in Chemical Systems, ed. R. J. Field and M. Burger, Wiley Interscience, New York, 1985 and references therein.
5. L. Treindl and R. M. Noyes, J. Phys. Chem., 1993, 97, 11354.
6. Lj. Kolar-Anic, Z. Cupic, S. Anic and G. Schmitz, J. Chem. Soc., Faraday Trans., 1997, 93, 2147.
7. G. Schmitz, J. Chim. Phys., 1987, 84, 957.
8. G. Laurenczy and M. T. Beck, J. Phys. Chem., 1994, 98, 5188.
9. F. G. Buchholtz and S. Broecker, J. Phys. Chem. A, 1998, 102, 1556.
10. P. Sevcik and L. Adamcikova, J. Phys. Chem., 1998, 102, 1288.
11. M. Radenkovic, G. Schmitz and Lj. Kolar-Anic, J. Serb. Chem. Soc., 1997, 62, 367.
12. M. Radenkovic, G. Schmitz and Lj. Kolar-Anic, Phys. Chem '98, 4th Int. Conf. Fundam. Appl. Aspects Phys. Chem., Society of Physical Chemists of Serbia, Belgrade, 1998, p. 195.
13. H. A. Liebhafsky, J. Am. Chem. Soc., 1931, 53, 2074.
14. H. A. Liebhafsky, W. C. MacGavock, R. J. Reyers, G. M. Roe and L. S. Wu, J. Am. Chem. Soc., 1978, 100, 87.
15. G. Schmitz, J. Chim. Phys., 1974, 71, 689.
16. G. Schmitz, Phys. Chem. Chem. Phys., 1999, 1, 1909.
17. H. A. Liebhafsky, J. Am. Chem. Soc., 1931, 53, 896.
18. W. C. Bray and H. A. Liebhafsky, J. Am. Chem. Soc., 1931, 53, 38.
19. H. A. Liebhafsky, J. Am. Chem. Soc., 1932, 54, 1792.
20. H. A. Liebhafsky and A. Mohammad, J. Am. Chem. Soc., 1933, 55, 3977.
21. C. Arias, F. Mata and J. F. Perez-Benito, Can. J. Chem., 1990, 68, 1499.
22. H. A. Liebhafsky, J. Am. Chem. Soc., 1932, 54, 3504.
23. I. Matsuzaki, R. Simic and H. A. Liebhafsky, Bull. Chem. Soc. Jpn., 1972, 45, 3367.
24. Lj. Kolar-Anic and G. Schmitz, J. Chem. Soc., Faraday Trans., 1992, 88, 2343.
25. J. Sigalla and C. Herbo, J. Chim. Phys., 1957, 54, 733.
26. M. Kaholek and L. Treindl, React. Kinet. Catal. Lett., 1998, 63, 297.
27. G. Schmitz, J. Chim. Phys., 1991, 88, 15.
28. B. L. Clarke, in Advances in Chemical Physics, ed. I. Prigogine and S. A. Rice, Wiley, New York, 1980, vol. XLIII, p. 1.
29. B. L. Clarke, Cell Biophys., 1988, 12, 237.
30. H. A. Liebhafsky and L. S. Wu, J. Am. Chem. Soc., 1974, 96, 7180.
31. K. R. Sharma and R. M. Noyes, J. Am. Chem. Soc., 1975, 97, 202.
32. P. Sevcik and L. Adamcikova, Chem. Phys. Lett., 1997, 267, 307.
33. J. Wang, F. Hynne, P. G. Sorensen and K. Nielsen, J. Phys. Chem., 1996, 100, 17593.
34. I. R. Epstein, Nature, 1995, 374, 321.