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DOI: 10.1039/A904192C (Paper) Reference Section for: Phys. Chem. Chem. Phys., 1999, 1, 5163-5167

A model of the anodic behaviour of iron in aqueous media

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Stephen V. Murphy and D. Brynn Hibbert

Abstract

An analysis of the dynamics of a model of the dissolution and passivation of iron is presented which explains (i) the pH dependence of the shape of the stationary anodic polarisation curve (V, i), (ii) the experimentally observed indeterminacy of the potential at which passivation takes place, (iii) the well defined reactivation of the electrode as the potential of the electrode is reduced below the Flade potential and (iv) the tendency for the current density to diminish as the electrolyte is made progressively less acidic.

References

  1. W. Allgaier and K. E. Heusler, Extended Abstract No. 94, Electrochem. Soc., 1973, 72–2236 Search PubMed.
  2. G. Bech-Nielson, Electrochim. Acta, 1982, 27, 1383 CrossRef.
  3. J. Bessone, L. Karakaya, P. Lorbeer and W. J. Lorenz, Electrochim. Acta, 1977, 22, 1147 CrossRef CAS.
  4. I. Epelboin and M. Keddam, J. Electrochem. Soc., 1970, 117, 1052.
  5. M. Keddam, O. R. Mattos and H. Takenouti, J. Electrochem. Soc., 1981, 128, 257 CAS.
  6. G. J. Bignold and M. Fleischmann, Electrochim. Acta, 1974, 19, 363 CrossRef CAS.
  7. W. Allgaier and K. E. Heusler, Z. Phys. Chem., 1975, 98, 161 CAS.
  8. V. Battaglia and J. Newman, J. Electrochem. Soc., 1995, 142, 1423 CAS.
  9. I. Epelboin, C. Gabrielli, M. Keddam, J.-C. Lestrade and H. Takenouti, J. Electrochem. Soc., 1972, 119, 1632 CAS.
  10. F. Flade, Z. Phys. Chem., 1911, 76, 513 CAS.
  11. M. Keddam, J.-F. Lizee, C. Pallotta and H. Takenouti, J. Electrochem. Soc., 1984, 131, 2016 CAS.
  12. P. Russell and J. Newman, J. Electrochem. Soc., 1986, 133, 2093 CAS.
  13. P. Russell and J. Newman, J. Electrochem. Soc., 1983, 130, 547 CAS.
  14. C. G. Law and J. Newman, J. Electrochem. Soc., 1979, 126, 2150 CAS.
  15. P. Russell and J. Newman, J. Electrochem. Soc., 1987, 134, 1051 CAS.
  16. P. Russell and J. Newman, J. Electrochem. Soc., 1986, 133, 59 CAS.
  17. D. B. Hibbert and S. V. Murphy, J. Electrochem. Soc., 1991, 138, L30 CAS.
  18. B. Rush and J. Newman, J. Electrochem. Soc., 1995, 142, 3770 CAS.
  19. M. Itagaki, R. Oltra, M. Keddam and H. Takenouti, J. Electrochem. Soc., 1997, 144, 64 CAS.
  20. C. Gabrielli, M. Keddam, F. Minouflet and H. Perrot, Electrochim. Acta, 1996, 41, 1217 CrossRef CAS.
  21. J. M. Blengino, M. Keddam, J. P. Labbe and L. Robbiola, Corros. Sci., 1995, 37, 621 CrossRef CAS.
  22. R. Oltra, G. M. Indrianjafy, M. Keddam and H. Takenouti, Corros. Sci., 1993, 35, 827 CrossRef CAS.
  23. C. Gabrielli and M. Keddam, Electroanal. Chem. Interfac. Electrochem., 1973, 45, 267 Search PubMed.
  24. K. E. Heusler, K. G. Weil and K. F. Bonhoeffer, Z. Phys. Chem., 1958, 15, 149 CAS.
  25. K. E. Heusler, Chem. Ing. Tech., 1964, 36, 589 CAS.
  26. K. E. Heusler and G. H. Cartledge, J. Electrochem. Soc., 1961, 108, 732 CAS.
  27. K. E. Heusler, Z. Elektrochem., 1958, 62, 582 Search PubMed.
  28. J. O'M. Bockris, D. Drazic and A. Despic, Electrochim. Acta, 1961, 4, 325 CrossRef CAS.
  29. J. O'M. Bockris and D. Drazic, Electrochim. Acta, 1962, 7, 293 CrossRef CAS.
  30. J. O'M. Bockris and H. Kita, J. Electrochem. Soc., 1961, 108, 676 CAS.
  31. J. O'M. Bockris and A. Damjanovic, Modern Aspects of Electrochemistry, No. 3, Butterworth, London, 1964, pp. 261–73 Search PubMed.
  32. K. E. Heusler, Encyclopedia of Electrochemistry of the Elements, ed. A. J. Bard, Marcel Dekker Inc., New York, 1982, vol. IX, part A, ch. 2 Search PubMed.
  33. I. Epelboin, C. Gabrielli, M. Keddam and H. Takenouti, Electrochim. Acta, 1975, 20, 913 CrossRef CAS.
  34. I. Epelboin and M. J. Keddam, Electrochim. Acta, 1972, 17, 177 CrossRef CAS.
  35. N. Sato and M. Cohen, J. Electrochem. Soc., 1964, 111, 512 CAS.
  36. M. Keddam, O. R. Mattos and H. Takenouti, J. Electrochem. Soc., 1981, 128, 266 CAS.
  37. W. J. Lorenz, A. A. El Milgy and D. Geana, Electrochim. Acta, 1975, 20, 273 CrossRef.
  38. P. Lorbeer and W. J. Lorenz, Corros. Sci., 1980, 20, 405 CAS.
  39. P. Lorbeer and W. J. Lorenz, Electrochim. Acta, 1980, 25, 375 CrossRef CAS.
  40. I. Epelboin, M. Keddam and J.-C. Lestrade, Faraday Discuss., 1974, 56, 264 Search PubMed.
  41. A. A. El Miligy, D. Geana and W. J. Lorenz, Electrochim. Acta, 1975, 20, 273 CrossRef.
  42. R. Gilmore, Catastrophe Theory for Scientists and Engineers, Wiley Interscience, New York, 1981 Search PubMed.
  43. T. Poston and I. Stewart, Catastrophe Theory and its Applications, Pitman Publishing Ltd, London, 1978 Search PubMed.
  44. U. F. Frank, Z. Naturforsch., 1949, 4a, 378 Search PubMed.
  45. H. H. Uhlig and P. F. King, J. Electrochem. Soc., 1959, 106, 1 CAS.
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