Critical behaviour of two-dimensional Lennard-Jones fluid mixtures: a mean field study

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Osvaldo H. Scalise, Guillermo J. Zarragoicoechea and Moises Silbert


Abstract

The critical behaviour of two-dimensional Lennard-Jones fluid binary mixtures is investigated by using thermodynamic perturbation theory. Preliminary results show that the critical curves for the two-dimensional mixtures exhibit the same behaviour as that found in the corresponding three-dimensional fluid binary mixtures, with similar shortcomings as those found in mean field theories.


References

  1. K. S. Birdi, Lipid and Biopolymer Monolayers at Liquid Interfaces, Plenum, New York, 1989 Search PubMed.
  2. A. W. Adamson and A. P. Gast, Physical Chemistry of Surfaces, Wiley, New York, 6th edn., 1997 Search PubMed.
  3. S. A. Safran, Statistical Mechanics of Surfaces, Interfaces and Membranes, Addison Wesley, Reading, MA, 1994 Search PubMed.
  4. O. H. Scalise, G. J. Zarragoicoechea, L. E. Gonzalez and M. Silbert, Mol. Phys., 1998, 93, 751 CrossRef CAS.
  5. O. H. Scalise, Phys. Chem. Liq., 1998, 36, 179 Search PubMed.
  6. G. J. Zarragoicoechea, Mol. Phys., 1999, 96, 1109 CrossRef CAS.
  7. F. Tsien and J. P. Valleau, Mol. Phys., 1974, 27, 177 CAS.
  8. S. Toxvaerd, J. Chem. Phys., 1978, 69, 4750 CrossRef CAS.
  9. D. Levesque and J. J. Weis, in Topics in Applied Physics, vol. 71, ed. K. Binder, Springer, Berlin, 1992, p. 121 Search PubMed.
  10. W. R. Smith, O. H. Scalise and T. W. Melnyk, Fluid Phase Equilib., 1989, 44, 237 CrossRef CAS.
  11. J. S. Rowlinson and F. L. Swinton, Liquids and Liquid Mixtures, Butterworth Scientific, London, 3rd edn., 1982 Search PubMed.
  12. J. Barker and D. Henderson, Rev. Mod. Phys., 1976, 48, 587 CrossRef CAS.
  13. D. J. Gonzalez, L. E. Gonzalez and M. Silbert, Mol. Phys., 1991, 74, 613 CAS.
  14. D. Henderson, Mol. Phys., 1977, 34, 301 CAS.
  15. J. J. Erpenbeck and M. Luban, Phys. Rev. A, 1985, 32, 2920 CrossRef CAS.
  16. O. H. Scalise, G. J. Zarragoicoechea, A. E. Rodríguez and R. D. Gianotti, J. Chem. Phys., 1987, 86, 6432 CrossRef CAS.
  17. R. L. Scott and P. van Konynenburg, Discuss. Faraday Soc., 1970, 49, 87 RSC.
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