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DOI: 10.1039/A901576K (Paper) Reference Section for: Phys. Chem. Chem. Phys., 1999, 1, 2411-2414

Kinetic investigation of the reaction between the NO3 radical and peroxymethacrylic nitric anhydride (MPAN)

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C E. Canosa-Mas, M D. King, D E. Shallcross and R P. Wayne

Abstract

The gas-phase reaction between the NO3 radical and peroxymethacrylic nitric anhydride (MPAN: (CH22C(CH3)C(O)O2NO2) has been studied by a relative-rate method at atmospheric pressure. A value of (1.45±0.45)×10-16 c molecule-1 s-1 was obtained for the rate constant. The atmospheric chemistry of MPAN was considered in a diurnally varying model of the planetary boundary layer.

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