Magnetic susceptibility of aqueous tert-butanol

(Note: The full text of this document is currently only available in the PDF Version )

Kazuko Mizuno, Torayuki Ochi, Shinji Shimada, Yukari Nishimura, Shiro Maeda and Yoshikata Koga


Abstract

Magnetic susceptibilities of aqueous tert-butanol were measured by the external double reference NMR method of Momoki and Fukazawa Reflecting a non-ideal volumetric behaviour of this mixture the volume susceptibility data shows a large non-ideal composition dependence. On the other hand, the molar magnetic susceptibility exhibits a small but finite deviation from ideality. Thus, an intra-molecular property, diamagnetic susceptibility, is not completely free from the effect of a non-ideal molecular arrangement in the mixture.


References

  1. K. Momoki and Y. Fukazawa, Anal. Chem., 1990, 62, 1665 CrossRef CAS.
  2. K. Momoki and Y. Fukazawa, Anal. Sci., 1994, 10, 53 CAS.
  3. H. E. Stanley, Introduction to Phase Transitions and Critical Phenomena, Oxford University Press, New York and Oxford, 1971, ch. 2 Search PubMed.
  4. F. Franks and D. J. G. Ives, Q. Rev. Chem. Soc., 1966, 20, 1 RSC.
  5. Water – A comprehensve treatise, ed. F. Franks, Plenum Press, New York, 1973–1995, vol. 2 and 4 Search PubMed.
  6. F. Franks and J. E. Desnoyers, in Water Science Reviews I, ed. F. Franks, Cambridge University Press, Cambridge, 1985, p. 175 Search PubMed.
  7. M. Nakagawa, H. Inubushi and T. Moriyoshi, J. Chem. Thermodyn., 1981, 13, 171 CAS.
  8. C. DeVisser, G. Perron and J. E. Desnoyers, Can. J. Chem., 1977, 55, 856 CAS.
  9. J. Lara and J. E. Desnoyers, J. Solution Chem., 1981, 10, 465 CrossRef CAS.
  10. J. F. Alary, M. A. Simard, J. Dumont and C. Jolicoeur, J. Solution Chem., 1982, 11, 755 CAS.
  11. F. Franks and H. T. Smith, Trans. Faraday Soc., 1968, 64, 2962 RSC.
  12. Y. Koga, J. Crystallogr. Soc. Jpn., 1995, 37, 172 Search PubMed.
  13. Y. Koga, J. Phys. Chem., 1996, 100, 5172 CrossRef CAS.
  14. Y. Koga, Can. J. Chem., 1986, 64, 206 CAS.
  15. Y. Koga, Can. J. Chem., 1988, 66, 1187 CAS.
  16. Y. Koga, Can. J. Chem., 1988, 66, 3171 CAS.
  17. Y. Koga, W. W. Y. Siu and T. Y. H. Wong, J. Phys. Chem., 1990, 94, 7700 CrossRef CAS.
  18. Y. Koga, T. Y. H. Wong and W. W. Y. Siu, Thermochim. Acta, 1990, 169, 27 CrossRef CAS.
  19. S. H. Tanaka, H. I. Yoshihara, A. W.-C. Ho, F. W. Lau, P. Westh and Y. Koga, Can. J. Chem., 1996, 74, 713 CAS.
  20. R. Cini and M. Torrini, J. Chem. Phys., 1968, 49, 2826 CAS.
  21. Handbook of Chemistry and Physics, ed. R. C. Weast, CRC Press, Cleveland, 54th edn., 1973–74, p. E-125 Search PubMed.
  22. M. Sakurai, K. Nakamura and K. Nitta, Bull. Chem. Soc. Jpn., 1994, 67, 1580 CAS.
  23. Handbook of Chemistry and Physics, ed. D. R. Lide, CRC Press, New York, 77th edn., 1996–97, p. 8–57 Search PubMed.
  24. M. Sakurai, Bull. Chem. Soc. Jpn., 1987, 60, 1 CAS.
  25. Y. Koga, K. Tamura and S. Murakami, J. Solution Chem., 1995, 24, 1125 CAS.
  26. Y. Koga and P. Westh, Bull. Chem. Soc. Jpn., 1996, 69, 1505 CAS.
Click here to see how this site uses Cookies. View our privacy policy here.