[1 + 4]-Cycloaddition of a stable silylene to 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene

Abstract

The stable bis(amino)silylene Si[(NCH₂Bu^t)₂C₆H₄-1,2] 1 undergoes [1 + 4]-cycloaddition with 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene 2 to afford compound 3: the molecular structure of 3 is supported by NMR spectroscopic data and confirmed by a single crystal X-ray diffraction study.

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