One step synthesis of [7]metacyclophanediyne complexes from bis(propargyldicobalt) dication equivalents

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Richard Guo and James R. Green


Abstract

The BF3·OEt2 mediated addition reactions of electron-rich arenes to 1,3-dialkoxyhepta-2,5-diyne(dodecacarbonyl)- tetracobalt complex 1 directly afford [7]metacyclophanediyne(dodecacarbonyl)tetracobalt complexes.


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