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DOI: 10.1039/A907476G (Paper) Reference Section for: Chem. Commun., 1999, 2525-2526

Selective binding of substrates using sodium salts of linked C3 symmetric aryl oxides

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Maarten B. Dinger and Michael J. Scott

Abstract

Tris(3,5-dialkyl-2-hydroxyphenyl)methanes (tert-butyl, tert-pentyl) react with three equivalents of sodium hydride to give hexanuclear dimers; these bulky aggregates have six well-defined coordination ‘pockets’ which demonstrate selectivity toward a variety of ketones.

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