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DOI: 10.1039/A907237C (Paper) Reference Section for: Chem. Commun., 1999, 2351-2352

Sterically induced transmutations in cobalt amine chemistry†

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Rodney J. Geue, C. Jin Qin, Stephen F. Ralph, Alan M. Sargeson, Anthony C. Willis, Rodney J. Geue, Alan M. Sargeson, Brian W. Skelton and Allan H. White

Abstract

Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to CoIII/IIN6 redox potentials close to +0.8 V (vs. SHE) and CoII hexaamine complexes that are air and substitution stable.

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