A highly enantioselective addition reaction of a chiral allylsilane to an activated N-acylisoquinolinium ion

Abstract

The addition reactions of a chiral allylsilane to activated N-acylisoquinolinium ions proceeded in a highly enantioselective manner (more than 90%) to afford homochiral 1-allyl-1,2-dihydroisoquinolines in good yields.

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