A new bifunctional ligand: C₅Me₄SiMe₂OSiMe₂O^2–. Synthesis, properties and crystal structure of the first Yb(II) half-sandwich complex with a heterobidentate cyclopentadienyl ligand, [{(η⁵-C₅Me₄)SiMe₂OSiMe₂(η¹-O)}Yb(thf)]₂

Abstract

The synthesis and crystal structure of the Yb(II) half-sandwich complex [{(η⁵-C₅Me₄)SiMe₂OSiMe₂(η¹-O)}Yb(thf)]₂ containing the new linked tetramethylcyclopentadienyl-silanolate ligand C₅Me₄SiMe₂OSiMe₂O^2– are reported.

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