Chemistry in interphases. The solid-phase synthesis of well defined rhodium and iridium phosphine complexes†

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Joachim Büchele and Hermann A. Mayer


Abstract

After polyethylene glycol functionalized metal complexes were supported by the sol–gel technique the organometallic protection group was eliminated in a combined photochemical/oxidative procedure and the immobilized non-coordinated ligand was treated with organometallic fragments to give new supported well defined rhodium and iridium complexes.


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