Fine-tuning of pore size of MCM-41 by adjusting the initial pH of the synthesis mixture

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Anjie Wang and Toshiaki Kabe


Abstract

The pore size of MCM-41 can be finely tuned from 38.3 to 52.7 Å with a narrow distribution by carefully adjusting the initial pH of the synthesis mixture from 11.5 to 10.0.


References

  1. J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T.-W. Chu, D. H. Olson, E. W. Sheppard, S. B. McCullen, J. B. Higgins and J. L. Schlenker, J. Am. Chem. Soc., 1992, 114, 10834 CrossRef CAS.
  2. A. Sayari, Y. Yang, M. Kruk and M. Jaroniec, J. Phys. Chem. B, 1999, 103, 3651 CrossRef CAS.
  3. Q. Huo, D. I. Margolese and G. D. Stucky, Chem. Mater., 1996, 8, 1147 CrossRef CAS.
  4. C. Cheng, W. Zhou, D. H. Park, J. Klinowski, M. Hargreaves and L. F. Gladden, J. Chem. Soc., Faraday Trans., 1997, 93, 359 RSC.
  5. M. Kruk, M. Jaroniec and A. Sayari, J. Phys. Chem. B, 1999, 103, 4590 CrossRef CAS.
  6. A. Corma, Q. Kan, M. T. Navarro, J. Pérez-Pariente and F. Rey, Chem. Mater., 1997, 9, 2123 CrossRef CAS.
  7. X. Chen, L. Huang and Q. Li, J. Phys. Chem. B, 1997, 101, 8460 CrossRef CAS.
  8. M. Kruk, M. Jaroniec and A. Sayari, Langmuir, 1997, 13, 6267 CrossRef CAS.
  9. Q. Huo, D. I. Margolese, U. Ciesla, P. Feng, T. E. Gier, P. Sieger, R. Leon, P. M. Petroff, F. Schüth and G. D. Stucky, Nature, 1994, 368, 317 CrossRef CAS.
  10. A. Monnier, F. Schüth, Q. Huo, D. Kumar, D. Margolese, R. S. Maxwell, G. D. Stucky, M. Krishnamurty, P. Petroff, A. Firouzi, M. Janicke and B. F. Chmelka, Science, 1993, 261, 1299 CrossRef CAS.
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