Construction of tetracyclic ring systems by Co2(CO)8-catalyzed tandem [2 + 2 + 1]/[2 + 2 + 2] cycloaddition reaction of diynes: a simple one-pot reaction†

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Soon Hyeok Hong, Jong Wook Kim, Dai Seung Choi, Young Keun Chung and Sueg-Geun Lee


Abstract

The Co2(CO)8-catalyzed tandem [2 + 2 + 1]/[2 + 2 + 2] cycloaddition reaction of terminal diynes under CO produces an unnatural novel tetracyclic compound.


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