View PDF Version
 
DOI: 10.1039/A905323I (Paper) Reference Section for: Chem. Commun., 1999, 1833-1834

α-[NH3(CH2)5NH3]SnI4: a new layered perovskite structure

(Note: The full text of this document is currently only available in the PDF Version )

Jun Guan, Zhongjia Tang and Arnold M. Guloy

Abstract

The synthesis and crystal structure of new organic–inorganic layered material, α-[NH3(CH2)5SnI4, is reported, which features an unprecedented <330>-terminated layered perovskite structure.

References

  1. (a) L. J. de Jongh and A. R. Miedema, Adv. Phys., 1974, 23, 1 CAS; (b) G. F. Needham, R. D. Willet and H. F. Franzen, J. Phys. Chem., 1984, 88, 674 CrossRef CAS; (c) P. Day, Philos. Trans. R. Soc. London A, 1985, 314, 145 Search PubMed; (d) T. Ishihara, J. Takahashi and T. Goto, Phys. Rev. B, 1990, 42, 11 099 CrossRef CAS; (e) J. Calabrese, N. L. Jones, R. L. Harlow, D. Thorn and Y. Wang, J. Am. Chem. Soc., 1991, 113, 2328 CrossRef CAS.
  2. G. C. Papavassiliou, I. B. Koutselas, A. Terzis and M. H. Whangbo, Solid State Commun., 1994, 91, 695 CrossRef CAS; G. C. Papavassiliou, in Nanophase Materials, ed. G. C. Hadjipanayis and R. W. Siegel, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994, pp. 493–502 and references therein Search PubMed.
  3. B. Tieke and G. Wegner, Angew. Chem., Int. Ed. Engl., 1984, 20, 687 CrossRef.
  4. D. B. Mitzi, C. A. Feild, W. T. A. Harrison and A. M. Guloy, Nature, 1994, 369, 467 CrossRef CAS.
  5. D. B. Mitzi, S. Wang, C. A. Feild, C. A. Chess and A. M. Guloy, Science, 1995, 267, 1473 CAS.
  6. J. G. Bednorz and K. A. Mueller, Z. Phys. B, 1986, 64, 189 CAS.
  7. A. J. Millis, B. I. Shraiman and R. Mueller, Phys. Rev. Lett., 1996, 77, 175 CrossRef CAS.
  8. R. J. Cava, Phys. Rev. B: Condens. Matter, 1992, 46, 14 101 Search PubMed.
  9. (a) A. J. Jacobson, in Chemical Physics of Intercalation II, ed. P. Bernier, J. E. Fischer, S. Roth and S. A. Solin, Plenum Press, New York, 1993, pp. 117–139 and references therein Search PubMed; (b) C. N. R. Rao and B. Raveau, Transition Metal Oxides, Wiley-VCH, New York, 2nd edn., 1998, pp. 38–220 Search PubMed.
  10. J. Guan, Z. Tang and A. M. Guloy, unpublished work.
  11. Single crystal X-ray analysis, using a Siemens SMART diffractometer equipped with a CCD detector was carried out at –50 °C. Monochromatized Mo-Kα radiation was used to collect a hemisphere of data. Empirical absorption correction was applied and redundant reflections were averaged. Laue photos and systematic absences unambiguously indicated the space group to be Pbcn. The final cell constants are: a= 30.255(2), b= 12.352(7), c= 25.6706(14)Å, V= 9593.0(5)Å3. Other relevant crystallographic data are: M= 730.49, Z= 24, µ= 9.291 mm–1, 2θmax= 48.40°; total data collected, 44333; independent reflections, 8381; observed reflections ( > 3σI), 7618; total variables, 309. The final Rindices, [I > 4σ(I)]: R1 = 0.0506, wR2 = 0.1282; (all data): R1 = 0.0691, wR2 = 0.1432. The structure was solved by direct methods and refined by full-matrix least-squares calculations. Thermal parameters of all non-hydrogen atoms were treated anisotropically. Five carbon sites (C3, C4, C13, C14, C15) exhibited conformational disorder and were refined based on a rotational disorder model. All hydrogen atoms were treated with a riding model (dC–H =dN–H = 0.89 Å, Uiso= 0.050). CCDC 182/1361.
  12. S. Wang, D. B. Mitzi, C. A. Feild and A. M. Guloy, J. Am. Chem. Soc., 1995, 117, 5297 CrossRef CAS.
  13. E. L. Eliel, Stereochemistry of Carbon Compounds, McGraw-Hill, Singapore, 1962, pp. 124–179 Search PubMed.
  14. J. del Hoyo, MS thesis, University of Houston, USA, 1997.
Click here to see how this site uses Cookies. View our privacy policy here.