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DOI: 10.1039/A905001I (Paper) Reference Section for: Chem. Commun., 1999, 1667-1668

A linear metal string [Cr7(µ7-teptra)4Cl2] complex with delocalized heptachromium(II) multiple bonds (teptraH3 = tetrapyridyltriamine)

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Yu-Hua Chen, Chung-Chou Lee, Chih-Chieh Wang, Gene-Hsiang Lee, Shie-Yang Lai, Feng-Yin Li, Chung-Yuan Mou and Shie-Ming Peng

Abstract

A heptachromium(II) metal chain helically wrapped by four all-syn type teptra3– ligands with delocalized CrII–CrII–CrII–CrII–CrII–CrII–CrII multiple bonds is found in the complex [Cr7(µ7-teptra)4Cl2]. The band structure of a hypothetical one-dimensional chromium string based on this structure is calculated and shows metallic behavior for the string structure.

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