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DOI: 10.1039/A903954F (Paper) Reference Section for: Chem. Commun., 1999, 1865-1866

Redox chemistry of cerocene: the first heterobimetallic organolanthanide complex†

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Ulrike Reißmann, Peter Poremba, Lutz Lameyer, Dietmar Stalke and Frank T. Edelmann

Abstract

The first heterobimetallic organolanthanide complex containing two different rare earth elements, [Yb(thf)6][Ce- (cot′′′)2]2 2 [cot′′′ = η8-1,3,6-(Me3Si)3C8H5], has been prepared by reacting neutral [Ce(cot′′′)2] with Yb metal in THF; the crystal structure of 2 consists of separated [Yb(thf)6]2+ and [Ce(cot′′′)2]– ions.

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