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DOI: 10.1039/A903740C (Paper) Reference Section for: Chem. Commun., 1999, 1405-1406

Enantiospecific synthesis of a planar chiral bidentate indenyl–alkoxide complex of zirconium using an axially chiral indene ligand

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Robert W. Baker and Brian J. Wallace

Abstract

The reaction of axially chiral (M)-1-(2′-methyl-3′-indenyl)- naphthalene-2-methanol 3 with Zr(NEt2)4 enantiospecifically provides the planar chiral complex (P)-bis(diethylamido)-[1-(2′-methyl-1′-indenyl)naphthalene-2-methoxo]- zirconium 7.

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