Novel cyclic hexanuclear complexes containing quadruply bonded units joined by µ6-carbonate ions

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Maw-Cherng Suen, Gwo-Wei Tseng, Jhy-Der Chen, Tai-Chiun Keng and Ju-Chun Wang


Abstract

Three complexes {[trans-Mo2(O2CCF3)2(µ-dppa)]36-CO3)(µ2-X)3}F [X = Cl, Br or I; dppa = N,N-bis(diphenylphosphino)amine], are reported, which are the first cyclic, hexanuclear complexes containing quadruply bonded units joined by carbonate ions.


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