View PDF Version
 
DOI: 10.1039/A902497B (Paper) Reference Section for: Chem. Commun., 1999, 1417-1418

Thiacrown ether tetrathiafulvalene derivatives as redox responsive ligands

(Note: The full text of this document is currently only available in the PDF Version )

Franck Le Derf, Miloud Mazari, Nicolas Mercier, Eric Levillain, Alain Gorgues, Marc Sallé, Pascal Richomme, Jan Becher, Javier Garín and Jesus Orduna

Abstract

Thiacrown ether TTF derivatives have been synthesized; one of them, whose X-ray molecular structure has been determined, is shown to combine Ag+ recognition and reversible binding properties as a function of the electrochemical potential applied.

References

  1. For a recent review, see: P. L. Boulas, M. Gómez-Kaifer and L. Echegoyen, Angew. Chem. Int. Ed., 1998, 37, 216 Search PubMed.
  2. (a) For a recent review, see: M. Brøndsted and J. Becher, Liebigs Ann., 1997, 2177 Search PubMed; (b) R. Dieing, V. Morisson, A. J. Moore, L. Goldenberg, M. R. Bryce, J. M. Raoul, M. C. Petty, J. Garin, M. Saviron, I. K. Lednev, R. E. Hester and J. N. Moore, J. Chem. Soc., Perkin Trans. 2, 1996, 1587 RSC.
  3. F. Le Derf, M. Mazari, M. Sallé, N. Mercier, E. Levillain, P. Richomme, J. Becher, J. Garin, J. Orduna and A. Gorgues, submitted.
  4. F. Le Derf, M. Sallé, N. Mercier, J. Becher, P. Richomme, A. Gorgues, J. Orduna and J. Garin, Eur. J. Org. Chem., 1998, 1861 CrossRef CAS.
  5. (a) M. Wagner, S. Zeltner and R. M. Olk, Liebigs Ann., 1996, 551 CAS; (b) T. Jorgensen, B. Girmay, T. K. Hansen, J. Becher, A. E. Underhill, M. B. Hursthouse, M. E. Harman and J. D. Kilburn, J. Chem. Soc., Perkin Trans. 1, 1992, 2907 RSC; (c) S. Zeltner, R. M. Olk, M. Wagner and B. Olk, Synthesis, 1994, 1445 CrossRef CAS.
  6. H. T. Stock and R. M. Kellog, J. Org. Chem., 1996, 61, 3093 CrossRef CAS.
  7. M. Munakata, L. P. Wu, X. Gan, T. K. Sowa and Y. Suenaga, Mol. Cryst. Liq. Cryst., 1996, 284, 319 Search PubMed.
  8. AgCF3SO3 99+%, purchased from Aldrich.
  9. M. J. Hynes, J. Chem. Soc., Dalton Trans., 1993, 311 RSC.
  10. Addition of Cu(CF3SO3)2 or Hg(CF3CO2)2 to 3 in CH2Cl2–CH3CN led to oxidation of the ligand.
Click here to see how this site uses Cookies. View our privacy policy here.