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DOI: 10.1039/A902368B (Paper) Reference Section for: Chem. Commun., 1999, 971-972

Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under exceedingly mild conditions—a novel possibility of carbon dioxide activation†

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Ferenc Joó, Ferenc Joó, Levente Nádasdi, János Elek, Gábor Laurenczy and Levente Nádasdi

Abstract

Water soluble ruthenium(II)– and rhodium(I)–phosphine complexes catalyze the hydrogenation of aqueous HCO3– to HCO2– under mild conditions with turnover frequencies up to 262 TO h–1.

References

  1. Most recent reviews: D. Walther, M. Ruben and S. Rau, Coord. Chem. Rev., 1999, 182, 67 Search PubMed; X. Yin and J. R. Moss, Coord. Chem. Rev., 1999, 181, 27 CrossRef.
  2. P. G. Jessop, T. Ikariya and R. Noyori, Nature, 1994, 368, 231 CrossRef CAS.
  3. O. Kröcher, R. A. Köppel and A. Baiker, Chem. Commun., 1997, 453 RSC.
  4. (a) W. Leitner, Angew. Chem., 1995, 107, 2391 CrossRef; Angew. Chem., Int. Ed. Engl., 1995, 34, 2207 Search PubMed; (b) W. Leitner, E. Dinjus and F. Gassner, in Aqueous-Phase Organometallic Catalysis, ed. B. Cornils and W. A. Herrmann, Wiley-VCH, Weinheim, 1998, p. 486 Search PubMed.
  5. F. Joó and M. T. Beck, Magy. Kém. Foly., 1973, 79, 189 Search PubMed; F. Joó, Proc. 15th ICCC (Moscow, USSR, 1973), p. 556 Search PubMed.
  6. F. Joó and M. T. Beck, React. Kinet. Catal. Lett., 1975, 2, 257 CAS.
  7. F. Joó, J. Kovács, A. Cs. Bényei and Á. Kathó, Catal. Today, 1998, 42, 441 CrossRef CAS.
  8. (8, 10): Z. Tóth, F. Joó and M. T. Beck, Inorg. Chim. Acta., 1980, 42, 153 Search PubMed (9, 11): F. Joó, J. Kovács, Á. Kathó, A. C. Bényei, T. Decuir and D. J. Darensbourg, Inorg. Synth., 1998, 32, 1 CrossRef CAS (12): K.-C. Tin, N.-B. Wang, R.-X. Li, Y.-Z. Li and X.-J. Li, J. Mol. Catal. A: Chem., 1998, 137, 113 Search PubMed (13): D. J. Darensbourg, F. Joó, M. Kannisto and Á. Kathó, Organometallics, 1992, 11, 1990 CAS (14): F. Joó, L. Nádasdi, A. Cs. Bényei and D. J. Darensbourg, J. Organomet. Chem., 1996, 512, 45 Search PubMed.
  9. F. P. Pruchnik, P. Smolenski and I. Raksa, Pol. J. Chem., 1995, 69, 5.
  10. J. R. Delerno, L. M. Trefonas, M. Y. Darensbourg and R. J. Majeste, Inorg. Chem., 1976, 15, 816 CrossRef.
  11. H. Gamsjäger and R. K. Murmann, in Adv. Inorg. Bioinorg. Mech., 1983, 2, 343 Search PubMed.
  12. C. J. Stalder, S. Chao, D. P. Summers and M. S. Wrighton, J. Am. Chem. Soc., 1983, 105, 6318 CrossRef CAS.
  13. K. Kudo, N. Sugita and Y. Takezaki, Nippon Kagaku Kaishi, 1997, 302; Chem. Abstr., 1977, 86, 178068s Search PubMed.
  14. Y. Inoue, H. Izumida, Y. Sasaki and H. Hashimoto, Chem. Lett., 1976, 863 CAS.
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