A novel two-dimensional honeycomb-like bimetallic iron(III)–nickel(II) cyanide-bridged magnetic material [Ni(cyclam)]₃[Fe(CN)₆]₂·nH₂O(cyclam = 1,4,8,11-tetraazacyclodecane)

Abstract

The 2D honeycomb-like layered iron(III)–nickel(II) cyanide-bridged complex [Ni(cyclam)]₃[Fe(CN)₆]₂·nH₂O exhibits ferromagnetic intralayer and antiferromagnetic interlayer interactions; above 3 K the magnetic properties are typical of a metamagnet with H_c = 5000 G, whereas below 3 K a canted structure is formed, leading to a long range ferromagnetic ordering.

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