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DOI: 10.1039/A901876J (Paper) Reference Section for: Chem. Commun., 1999, 813-814

Unprecedented µ-1,2,3κS:4,5κN coordination mode of the thiocyanate anion in two new double salts of silver(I), AgSCN·2AgNO3 and AgSCN·AgClO4

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Guo-Cong Guo and Thomas C. W. Mak

Abstract

The double salts AgSCN·2AgNO3 and AgSCN·AgClO4 both feature an unprecedented µ5-1,2,3κS:4,5κN coordination mode of the thiocyanate ligand, which generates a two- or three-dimensional network according to the relative coordinating capability of the co-existing nitrate or perchlorate anion.

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