Unusual redox-type addition of nitroalkanes on the C60 surface

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Masatomi Ohno, Arihiro Yashiro, Yohei Tsunenishi and Shoji Eguchi


Abstract

Nitroethanes underwent base-catalyzed addition to C60 to give 2-hydroxy-1,2-dihydrofulleryl ketoximes by way of a unique intramolecular redox process, which is not observed in normal alkenes.


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