View PDF Version
 
DOI: 10.1039/A901644I (Paper) Reference Section for: Chem. Commun., 1999, 953-954

Synthesis and reactivity of the osmium methylidene complex [(C5Me5)Os([double bond, length half m-dash]CH2)(dppm)][OTf]

(Note: The full text of this document is currently only available in the PDF Version )

Julia L. Brumaghim and Gregory S. Girolami

Abstract

Treatment of the hydride complex (C5Me5)Os(dppm)H, [dppm = bis(diphenylphosphino)methane] with 2 equivalents of methyl trifluoromethanesulfonate (MeOTf) affords the methylidene complex [(C5Me5)Os([double bond, length half m-dash]CH2)(dppm)][OTf]; the molecular structure and dynamic NMR behavior of this methylidene complex are described.

References

  1. P. Schwab, R. H. Grubbs and J. W. Ziller, J. Am. Chem. Soc., 1996, 118, 100 CrossRef CAS.
  2. V. Dragutan, A. T. Balban and M. Dimonie, Olefin Metathesis and Ring-Opening Polymerization of Cyclo-Olefins, Wiley, New York, 1985 Search PubMed.
  3. W. J. Feast, The Chemistry of the Metal Carbon Bond, Wiley, New York, 1989, vol. 5 Search PubMed.
  4. R. H. Grubbs and W. Tumas, Science, 1989, 243, 907 CAS.
  5. K. J. Ivin, Olefin Metathesis, Academic Press, New York, 1983 Search PubMed.
  6. C. Pariya and K. N. Jayaprakash, Coord. Chem. Rev., 1998, 168, 1 CrossRef CAS.
  7. R. R. Schrock, Acc. Chem. Res., 1990, 23, 158 CrossRef CAS.
  8. H. Werner, A. Kletzin, P. W. Höhn, W. Knaup, M. L. Ziegler and O. Serhadli, J. Organomet. Chem., 1986, 306, 227 CrossRef CAS.
  9. R. R. Schrock, J. Am. Chem. Soc., 1975, 97, 6577 CrossRef CAS.
  10. A. K. Burrell, G. R. Clark, C. E. F. Rickard, W. R. Roper and A. H. Wright, J. Chem. Soc., Dalton Trans., 1991, 609 RSC.
  11. M. D. Fryzuk, X. Gao, K. Joshi, P. A. MacNeil and R. L. Massey, J. Am. Chem. Soc., 1993, 115, 10 581 CrossRef CAS.
  12. T. B. Gunnoe, P. S. White, J. L. Templeton and L. Casarrubios, J. Am. Chem. Soc., 1997, 119, 3171 CrossRef CAS.
  13. D. M. Heinekey and C. E. Radzewich, Organometallics, 1998, 17, 51 CrossRef CAS.
  14. A. Hill, W. R. Roper, J. M. Waters and A. H. Wright, J. Am. Chem. Soc., 1983, 105, 5939 CrossRef CAS.
  15. S. E. Kegley, M. Brookhart and G. R. Husk, Organometallics, 1982, 1, 760 CrossRef CAS.
  16. M. Oliván and K. G. Caulton, J. Chem. Soc., Chem. Commun., 1997, 1733 RSC.
  17. A. T. Patton, C. E. Strouse, C. B. Knobler and J. A. Gladysz, J. Am. Chem. Soc., 1983, 105, 5804 CrossRef.
  18. C. Roger and C. Lapinte, J. Chem. Soc., Chem. Commun., 1989, 1598 RSC.
  19. L. G. Chamberlain, I. P. Rothwell and J. C. Huffman, J. Am. Chem. Soc., 1986, 108, 1502 CrossRef CAS.
  20. C. L. Gross and G. S. Girolami, Organometallics, 1996, 15, 5359 CrossRef CAS.
  21. C. L. Gross and G. S. Girolami, J. Am. Chem. Soc., 1998, 120, 6605 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.