Photolytic induction of the asymmetric catalytic complexation of prochiral cyclohexa-1,3-dienes by the tricarbonyliron fragment1

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Hans-Joachim Knölker, Holger Hermann and Daniela Herzberg


Abstract

Photolytic induction of the asymmetric catalytic complexation of prochiral cyclohexa-1,3-dienes by the tricarbonyliron fragment using a camphor-derived azadiene catalyst provides the corresponding tricarbonyliron complexes quantitatively in up to 86% ee.


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