DOI: 10.1039/A901439J
(Paper)
Reference Section for: Chem. Commun., 1999, 943-944
Low temperature selective methane activation to alkenes by a new hydrogen-accumulating system
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M. V. Tsodikov, Ye. V. Slivinskii, V. P. Mordovin, O. V. Bukhtenko, G. Colón, M. C. Hidalgo and J. A. Navío
Abstract
A heterogeneous hydrogen-accumulating system containing porous titanium with 0.4 wt% Ni combined with high-purity titanium chips was tested for methane activation; methane conversion to C1–C4 hydrocarbons reached a value of ca. 20% over this material, working at 450 °C and 10 atm, after methane circulation across the system for 22 h; the split hydrogen was accumulated as TiH2, being in solid solution with porous metallic titanium.
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