Air-stable crystalline primary phosphines and germanes: synthesis and crystal structures of dibenzobarellenephosphine and tribenzobarellenegermane

Abstract

The syntheses of dibenzobarellenephosphine and tribenzobarellenegermane are described; at room temperature these primary phosphines and germanes form air-stable crystals whose structures are reported together with that of tribenzobarellenemethane.

References

1. P. G. Jones, H. W. Roesky, H. Grutzmacher and G. M. Sheldrick, Z. Naturforsch., Teil B, 1985, 40, 590; P. G. Edwards, J. S. Fleming, S. S. Liyanage, S. J. Coles and M. B. Hursthouse, J. Chem. Soc., Dalton Trans., 1996, 1801; R. J. Batchelor, T. Birchall and R. Faggiani, Can. J. Chem., 1985, 63, 928; R. Felsberg, S. Blaurock, S. Jelonek, T. Gelbrich, R. Kirmse, A. Voigt and E. Hey-Hawkins, Chem. Ber., 1997, 130, 807; I. V. Kourkine, S. V. Maslennikov, R. Ditchfield, D. S. Glueck, G. P. A. Yap, L. M. Liable-Sands and A. L. Rheingold, Inorg. Chem., 1998, 35, 1996; D. S. Bohle, G. R. Clark, C. E. F. Rickard, W. R. Roper and W. B. Shepard, J. Organomet. Chem., 1991, 402, 375; B. D. Zwick, M. A. Dewey, D. A. Knight, W. E. Buhro, A. M. Arif and J. A. Gladysz, Organometallics, 1992, 11, 2673; G. A. A. Hadi, K. Fromm, S. Blaurock, S. Jelonek and E. Hey-Hawkins, Polyhedron, 1997, 16, 721.
2. R. A. Barlett, M. M. Olmstead, P. P. Power and G. A. Sigel, Inorg. Chem., 1987, 26, 1941.
3. N. J. Goodwin, W. Henderson and B. K. Nicholson, Chem. Commun., 1997, 31.
4. G. Ramakrishnan, A. Jouaiti, M. Geoffroy and G. Bernardinelli, J. Phys. Chem., 1996, 100, 10 861.
5. L. Heuer, D. Schomburg and R. Schmutzler, Chem. Ber., 1989, 122, 1473.
6. D. J. Brauer, J. Fischer, S. Kuchen, K. P. Langhans and O. Stelzer, Z. Naturforsch., Teil B, 1994, 49, 1511.
7. M. Brynda, T. Berclaz, M. Geoffroy, G. Ramakrishnan and G. Bernardinelli, J. Phys. Chem., 1998, 102, 8245.
8. M. J. Barrow, E. A. V. Ebsworth, M. M. Harding and D. W. H. Rankin, J. Chem. Soc., Dalton Trans., 1980, 604.
9. F. Imashiro, T. Terao and A. Saika, J. Am. Chem. Soc., 1979, 101, 3762.
10. H. D. Flack, Acta Crystallogr., 1983, A39, 876; G. Bernardinelli and H. D. Flack, Acta Crystallogr., 1985, A41, 500.
11. G. R. Tian, S. Sugiyama, A. Mori and H. Takeshita, Sogo Rikogaku Hokoku (Kyushu Daigaku Daigakuin), 1988, 10, 171 (Chem. Abstr., 1990, 112).