Combinatorial and rapid screening approaches to homogeneous catalyst discovery and optimization

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Robert H. Crabtree


Abstract

Rapid screening and combinatorial chemistry are expected to influence the way homogeneous catalysts are discovered and developed.


References

  1. R. H. Crabtree, Acc. Chem. Res., 1979, 12, 331 CrossRef CAS .
  2. S. R. Wilson and A. W. Czarnik, Combinatorial Chemistry, Wiley, New York, ed. J. Szostak, Chem. Rev., 1997, 97, 347(Special issue on combinatorial chemistry) Search PubMed .
  3. C. M. Killian, D. J. Tempel, L. K. Johnson and M. Brookhart, J. Am. Chem. Soc., 1996, 118, 11 664 CrossRef CAS .
  4. (a) F. R. Hartley, Supported Metal Complexes. A New Generation of Catalysts, Riedel, Dordrecht, 1985 Search PubMed ; (b) R. B. Merrifield, J. Am. Chem. Soc., 1963, 85, 2149 CrossRef CAS .
  5. B. A. Bunin and J. Ellman, J. Am. Chem. Soc., 1992, 114, 10 997 CrossRef CAS .
  6. B. Jandeleit and W. H. Weinberg, Chem. Ind., 1998, 19, 795 ; W. H. Weinberg, B. Jandeleit, K. Self and H. Turner, Curr. Opin. Solid State Mater. Sci., 1998, 3, 104 CrossRef CAS .
  7. J. K. Borchardt, Today's Chemist at Work, 1998, 7(10), 35 Search PubMed .
  8. A. C. Cooper, L. H. McAlexander, D.-H. Lee, M. T. Torres and R. H. Crabtree, J. Am. Chem. Soc., 1998, 120, 9971 CrossRef CAS .
  9. S. J. Taylor and J. P. Morken, Science, 1998, 280, 267 CrossRef CAS  See also: M. T. Reetz, M. H. Becker, K. M. Kühling and A. Holzwarth, Angew. Chem., Int. Ed., 1998, 37, 2647 Search PubMed ; F. C. Moates, M. Somani, J. Annamalai, J. T. Richardson, D. Luss and R. C. Wilson, Ind. Eng. Chem. Res., 1996, 35, 4801 CrossRef CAS .
  10. A. Holzwarth, P. W. Schmidt and W. E. Maier, Angew. Chem., Int. Ed., 1998, 37, 2644 CrossRef .
  11. K. H. Shaughnessy, P. Kim and J. H. Hartwig, J. Am. Chem. Soc., 1999, 121, 2123 CrossRef CAS .
  12. G. T. Copeland and S. J. Miller, J. Am. Chem. Soc., 1999, 121, 4306 CrossRef CAS .
  13. S. M. Senkan, Nature, 1998, 394, 350 CrossRef CAS .
  14. M. S. Sigman and E. N. Jacobsen, J. Am. Chem. Soc., 1998, 120, 4901 CrossRef CAS .
  15. H. B. Kagan, J. Organomet. Chem., 1998, 567, 3 CrossRef CAS ; X. Gao and H. B. Kagan, Chirality, 1998, 10, 120 CrossRef CAS .
  16. K. Burgess, H.-J. Lim, A. M. Porte and G. A. Sulikowski, Angew. Chem., Int. Ed., 1996, 35, 220 CrossRef CAS .
  17. J. S. Früchtel and G. Jung, Angew. Chem., Int. Ed., 1996, 35, 17 CrossRef ; R. Epton, Innovation and Perspectives in Solid Phase Synthesis, Intercept, Andover, 1992 Search PubMed .
  18. M. B. Francis, N. S. Finney and E. N. Jacobsen, J. Am. Chem. Soc., 1996, 118, 8983 CrossRef CAS .
  19. M. H. J. Ohlmeyer, R. N. Swanson, L. W. Dillard, J. C. Reader, G. Asouling, R. Kobayashi, M. Wigler and W. C. Still, Proc. Natl. Acad. Sci., 1993, 90, 10 922 CAS .
  20. L. Canali, E. Cowan, H. Deleuze, C. L. Gibson and D. C. Sherrington, Chem. Commun., 1998, 2561 RSC .
  21. A. C. Cooper, J. A. Loch and R. H. Crabtree, J. Am. Chem. Soc., submitted Search PubMed ; A. C. Cooper, J. A. Loch, A. White and R. H. Crabtree, unpublished data .
  22. T. E. Mallouk, E. Reddington, C. Pu, K. L. Ley and E. S. Smotkin, Ext. Abstr., Fuel Cell Seminar, Orlando, FL, 1996p. 686 Search PubMed .
  23. R. F. Service, Science, 1997, 277, 474 CrossRef CAS ; E. Danielson, J. H. Golden, E. McFarland, C. M. Reaves, W. H. Weinberg and X. D. Wu, Nature, 1997, 389, 944 CrossRef CAS .
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