Oxidation catalysis over functionalized metalloporphyrins fixated within ultralarge-pore transition metal-doped silicate supports

(Note: The full text of this document is currently only available in the PDF Version )

Lei Zhang, Tao Sun and Jackie Y. Ying


Abstract

Amine-functionalized metalloporphyrins stably fixated on well-defined ultralarge-pore Nb-doped silicates provided excellent catalytic oxidation activity for bulky substrates.


References

  1. D. Ostovic, G. S. He and T. C. Bruice, in Metalloporphyrins in Catalytic Oxidations, ed. R. A. Sheldon, Marcel Dekker, New York, 1994, ch. 2 Search PubMed.
  2. B. Meunier, Chem. Rev., 1992, 92, 1411 CrossRef CAS.
  3. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli and J. S. Beck, Nature, 1992, 359, 710 CrossRef CAS; A. Monnier, F. Schüth, Q. Huo, D. Kumar, D. I. Margolese, R. S. Maxwell, G. D. Stucky, M. Krishnamurthy, P. Petroff, A. Firouzi, M. Janicke and B. F. Chmelka, Science, 1993, 261, 1299 CrossRef CAS; P. T. Tanev and T. J. Pinnavaia, Science, 1995, 267, 865 CrossRef CAS; H. Yang, A. Kuperman, N. Coombs, S. Mamiche-Afara and G. A. Ozin, Science, 1996, 379, 703 CAS.
  4. C.-J. Liu, S.-G. Li, W.-Q. Pang and C.-M. Che, Chem. Commun., 1997, 65 RSC; C.-J. Liu, W.-Y. Yu, S.-G. Li and C.-M. Che, J. Org. Chem., 1998, 63, 7364 CrossRef CAS.
  5. B. T. Holland, C. Walkup and A. Stein, J. Phys. Chem. B, 1998, 102, 4301 CrossRef CAS.
  6. D. M. Antonelli and J. Y. Ying, Angew. Chem., Int. Ed. Engl., 1996, 35, 426 CrossRef CAS; D. M. Antonelli, A. Nakahira and J. Y. Ying, Inorg. Chem., 1996, 35, 3126 CrossRef CAS; D. M. Antonelli and J. Y. Ying, Chem. Mater., 1996, 8, 874 CrossRef CAS; T. Sun and J. Y. Ying, Nature, 1997, 389, 704 CrossRef CAS.
  7. L. Zhang and J. Y. Ying, AIChE J., 1997, 43, 2793 CrossRef CAS.
  8. J. Collman, R. R. Gagne, C. A. Reed, T. R. Halbert, G. Lang and W. T. Robinson, J. Am. Chem. Soc., 1975, 97, 1427 CrossRef CAS.
  9. P. Rothemund, J. Am. Chem. Soc., 1939, 2012.
  10. J. T. Groves and D. V. Subramanian, J. Am. Chem. Soc., 1984, 106, 2177 CrossRef CAS.
  11. D. R. Leanord and J. R. Lindsay Smith, J. Chem. Soc., Perkin Trans. 2, 1990, 1917 RSC.
Click here to see how this site uses Cookies. View our privacy policy here.