View PDF Version
 
DOI: 10.1039/A900302I (Paper) Reference Section for: Chem. Commun., 1999, 745-746

Unprecedented nitrosyl-bridged double-A-frame triplatinum complexes, [Pt3(µ-triphosphine)2(µ-NO)2(RNC)2](BF4)4

(Note: The full text of this document is currently only available in the PDF Version )

Tomoaki Tanase, Makiko Hamaguchi, Rowshan Ara Begum, Shigenobu Yano and Yasuhiro Yamamoto

Abstract

Reaction of linear triplatinum complexes, linear-[Pt3(µ-dpmp)2(RNC)2](PF6)2 1, with an excess of [NO][BF4] afforded an unprecedented nitrosyl-bridged double-A-frame triplatinum complexes, [Pt3(µ-dpmp)2(µ-NO)2(RNC)2](BF4)4 [2a: R = 2,6-xylyl; 2b: R = 2,4,6-mesityl, dpmp = bis(diphenylphosphinomethyl)phenylphosphine], which were characterized by X-ray crystallographic analysis and extended Hückel MO calculations.

References

  1. A. L. Balch, Prog. Inorg. Chem., 1994, 41, 239 CAS and references therein R. J. Puddephatt, L. Manojlovic-Muir and K. W. Muir, Polyhedron, 1990, 9, 2767 Search PubMed and references therein.
  2. T. Tanase, H. Ukaji, H. Takahata, H. Toda, T. Igoshi and Y. Yamamoto, Organometallics, 1998, 17, 196 CrossRef CAS.
  3. T. Tanase, H. Takahata, M. Hasegawa and Y. Yamamoto, J. Organomet. Chem., 1997, 545/546, 531 CrossRef.
  4. T. Tanase, H. Toda and Y. Yamamoto, Inorg. Chem., 1997, 36, 1571 CrossRef CAS.
  5. T. Tanase, H. Toda, K. Kobayashi and Y. Yamamoto, Organometallics, 1996, 15, 5272 CrossRef CAS.
  6. T. Tanase, H. Ukaji, T. Igoshi and Y. Yamamoto, Inorg. Chem., 1996, 14, 4114 CrossRef CAS.
  7. (a) F. Neve, M. Ghedini, A. Tirpicchio and F. Ugozzoli, Organometallics, 1992, 11, 795 CrossRef CAS; (b) M. Ghedini, F. Neve, C. Mealli, A. Tirpicchio and F. Ugozzoli, Inorg. Chim. Acta, 1990, 178, 5 CrossRef CAS.
  8. K. A. Azam, A. A. Frew, B. R. Lloyd, L. Manojlovic-Muir, K. W. Muir and R. J. Puddephatt, Organometallics, 1985, 4, 1400 CrossRef CAS.
  9. T. S. Cameron, P. A. Gardner and K. R. Grundy, J. Organomet. Chem., 1981, 212, C19 CrossRef CAS.
  10. J. H. Enemark and R. D. Feltham, Coord. Chem. Rev., 1974, 13, 339 CrossRef CAS.
  11. D. M. Hoffman and R. Hoffmann, Inorg. Chem., 1981, 20, 3543 CrossRef CAS.
  12. R. Hoffman, J. Chem. Phys., 1963, 39, 1397 CrossRef CAS.
  13. R. Hoffmann and W. N. Lipscomb, J. Chem. Phys., 1962, 36, 2179 CrossRef CAS.
  14. R. Hoffmann and W. N. Lipscomb, J. Chem. Phys., 1962, 36, 3489 CrossRef.
  15. J. H. Ammeter, H.-B. Burgi, J. C. Thibeault and R. Hoffmann, J. Am. Chem. Soc., 1978, 100, 3686 CrossRef CAS.
  16. C. Mealli and D. Prosterpio, J. Chem. Educ., 1990, 67, 399 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.