DOI: 10.1039/A900166B
(Paper)
Reference Section for: Chem. Commun., 1999, 925-926
Hydrazinolysis of Fischer-type oxacarbenes made efficient: a new and easy entry to alkyl and aryl hydrazinocarbene complexes
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Emanuela Licandro, Stefano Maiorana, Antonio Papagni, Dario Perdicchia and Raffaella Manzotti
Abstract
Hydrazinolysis of the pentacarbonyl[alkyl- or aryl-(methoxy)carbene] complexes of W0 and Cr0 with both 1,1- and 1,2-disubstituted hydrazines affords the corresponding new hydrazinocarbenes 15–18, 21 and 22, and the presence of LiCl in the reaction medium greatly increases their yields.
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- Results to be published.
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