DOI: 10.1039/A900023B
(Paper)
Reference Section for: Chem. Commun., 1999, 643-644
Characterisation of a dodecanuclear chromium(III) cage with an S = 6 ground state
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Mark Murrie, Simon Parsons, Richard E. P. Winpenny, Frank E. Mabbs, Eric J. L. McInnes, Chick C. Wilson and Graham M. Smith
Abstract
Neutron diffraction, magnetic susceptibility and EPR spectroscopic studies of a dodecanuclear chromium cage are reported which show the molecule has an S = 6 spin ground state; this is the highest spin ground state known for a cage of this metal.
References
- R. Sessoli, H.-L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou and D. N. Hendrickson, J. Am. Chem. Soc., 1993, 115, 1804 CrossRef CAS; R. Sessoli, D. Gatteschi, A. Caneschi and M. A. Novak, Nature, 1993, 365, 141 CrossRef CAS.
- S. M. J. Aubin, M. W. Wemple, D. M. Adams, H.-L. Tsai, G. Christou and D. N. Hendrickson, J. Am. Chem. Soc., 1996, 118, 7746 CrossRef CAS.
- C. Sangregorio, T. Ohm, C. Paulsen, R. Sessoli and D. Gatteschi, Phys. Rev. Lett., 1997, 78, 4645 CrossRef CAS.
- Z. Sun, C. M. Grant, S. L. Castro, D. N. Hendrickson and G. Christou, Chem. Commun., 1998, 721 RSC.
- A. S. Batsanov, G. A. Timko, Y. T. Struchkov, N. V. Gérbéléu and K. M. Indrichan, Koord. Khim., 1991, 17, 662 Search PubMed.
- P. T. Beurskens, G. Beurskens, W. P. Bosman, R. de Gelder, S. Garcia-Granda, R. O. Gould, R. Israel and J. M. M. Smits, DIRDIF-96 program system, University Crystallography Laboratory, University of Nijmegen, 1996.
- G. M. Sheldrick, University of Göttingen, 1997.
- C. C. Wilson, J. Mol. Struct., 1997, 405, 207 CrossRef CAS.
- A.-L. Barra, L.-C. Brunel, D. Gatteschi, L. Pardi and R. Sessoli, Acc. Chem. Res., 1998, 31, 460 CrossRef CAS.