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DOI: 10.1039/A900002J (Paper) Reference Section for: Chem. Commun., 1999, 389-390

Synthesis and X-ray structure of a cluster complex with facial coordination of cyclooctatetraene to a Co2Ni triangle

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Hubert Wadepohl, Stefan Gebert, Rüdiger Merkel and Hans Pritzkow

Abstract

The reaction between [(η-C5H5)NiCo3(CO)9] and cyclooctatetraene yields [Co2Ni(CO)6(µ3-η2:η3:η3-C8H8)] with a cyclooctatetraene ligand in the facial coordination mode to a heterometallic Co2Ni triangle.

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