Control of proton transfer by hydrogen bonding in the protonated forms of the binucleophilic complex [{η5-C5H4CH(CH2)4NMe}Ir(PPh3)H2]

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M. Mar Abad, Isabelle Atheaux, André Maisonnat and Bruno Chaudret


Abstract

Proton transfer reactions between both nucleophilic sites of a dihydrido iridium complex containing the 4-N-methylpiperidylcyclopentadienyl ligand and their dependance with the hydrogen bonding ability of the solvent medium are studied by NMR.


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