Rate constants for the reaction of cumylperoxyl radicals with Bu3SnH and (TMS)3SiH

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Chryssostomos Chatgilialoglu, Vitaliy I. Timokhin, Andriy B. Zaborovskiy, Daria S. Lutsyk and Ruslan E. Prystansky


Abstract

The rate constants for the reaction of a cumylperoxyl radical with Bu3SnH and (TMS)3SiH were determined at 72.5 °C to be 1600 and 66 M–1 s–1, respectively, by using inhibited hydrocarbon oxidation methodologies.


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